borane 9-(diphenylphosphanyl)[7]helicene complex | 1444418-25-0

• 英文名称: borane 9-(diphenylphosphanyl)[7]helicene complex
• CAS: 1444418-25-0
• 化学式: C₄₂H₃₀BP
• 分子量: 576.485
• InChiKey: YXPPMBZLMZHBBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dimethyl sulfide borane 、 9-Bromo<7>helicene 、 二苯基膦 在 trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) 、 potassium acetate 作用下， 以 四氢呋喃 为溶剂， 反应 0.83h， 以52%的产率得到borane 9-(diphenylphosphanyl)[7]helicene complex
  参考文献：
  名称：

  Exploration of 9-bromo[7]helicene reactivity

  摘要：

  Exploration of 9-bromo[7]helicene reactivity mainly in Pd-catalyzed reactions is reported. Palladium catalyzed carbon-carbon and carbon-heteroatom coupling reactions provide a large portfolio of racemic helicenes bearing different functional groups in good to excellent yields. Many of the reactions were performed in the microwave reactor keeping reaction time to a minimum compared with conventional synthetic methods. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.05.039