[Zr(2,6-iPr2C6H3)NC(NMe2)N(SiMe3))(μ2-Cl)Cl2]2 | 1101893-76-8

• 英文名称: [Zr(2,6-iPr2C6H3)NC(NMe2)N(SiMe3))(μ2-Cl)Cl2]2
• CAS: 1101893-76-8
• 化学式: C₃₆H₆₄Cl₆N₆Si₂Zr₂
• 分子量: 1032.28
• InChiKey: UZPWXLKNPFJUCY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  氯化锆(IV) 、 lithium (2,6-diisopropylphenyl)(trimethylsilyl)amide 、 二甲基氢胺 以39%的产率得到[Zr(2,6-iPr2C6H3)NC(NMe2)N(SiMe3))(μ2-Cl)Cl2]2
  参考文献：
  名称：

  Synthesis, structure and catalytic properties of a novel zirconium guanidinato complex [Zr{ArNC(NMe2)N(SiMe3)}(μ2-Cl)Cl2]2[Ar=2,6-iPr2-C6H3]

  摘要：

  A novel non-symmetric zirconium guanidinato complex, [(Zr{ArNC(NMe2)N(SiMe3)}(mu(2)-Cl)Cl-2}(2)] (Ar = 2.6-Pr-i(2)-C6H3). was synthesized and structurally characterized. Catalytic studies showed that the zirconium complex was active for ethylene polymerization with the activity of 4.98 x 10(5) g PE/mol Zr h. The influences of cocatalysts, Al/Zr molar ratios and ethylene pressures on the activities were investigated. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.08.001