| 438225-69-5

• CAS: 438225-69-5
• 化学式: C₂₄H₂₀B*C₂₈H₅₆N₆O₂P₃U
• 分子量: 1158.98
• InChiKey: FTLMQNOCKGQRKG-HKLVTPKYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 triethylammonium tetraphenylborate 以 氘代四氢呋喃 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  The first mixed cyclooctatetraenyl-phospholyl metal complexes. Crystal structure of [U(η-C8H8)(η-C4Me4P)(BH4)(OC4H8)]

  摘要：

  Treatment of [U(COT)(BH4)(2)(THF)] (1) or [U(COT)(BH4)(THF)(2)][BPh4] (2) (COT = eta-C8H8) with Ktmp (tmp. eta-C4Me5P) gave [U(COT)(tmp)(BH4)(THF)] (4), the crystal structure of which was determined. Further reaction of Ktmp with 4 afforded the "ate" addition derivative K[U(COT)(tmp)(2)(BH4)(THF)(x)] Complex 4 was transformed into [U(COT)(tmp)(OEt)] (5) in the presence of NaOEt. The cationic compound [U(COT)(tmp)(HMPA)(2)][BPh4] (6) (HMPA, hexamethylphosphoramide) was isolated from the reaction of [U(COT)(HMPA)(3)][BPh4](2) (3) with Ktmp. The cationic complexes 2 and 3 were recovered upon protonation of 4 and 6 with NEt3HBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01250-5
• 作为产物：
  描述：

  、 potassium 2,3,4,5-tetramethylphospholide 以 四氢呋喃 为溶剂， 以81%的产率得到
  参考文献：
  名称：

  The first mixed cyclooctatetraenyl-phospholyl metal complexes. Crystal structure of [U(η-C8H8)(η-C4Me4P)(BH4)(OC4H8)]

  摘要：

  Treatment of [U(COT)(BH4)(2)(THF)] (1) or [U(COT)(BH4)(THF)(2)][BPh4] (2) (COT = eta-C8H8) with Ktmp (tmp. eta-C4Me5P) gave [U(COT)(tmp)(BH4)(THF)] (4), the crystal structure of which was determined. Further reaction of Ktmp with 4 afforded the "ate" addition derivative K[U(COT)(tmp)(2)(BH4)(THF)(x)] Complex 4 was transformed into [U(COT)(tmp)(OEt)] (5) in the presence of NaOEt. The cationic compound [U(COT)(tmp)(HMPA)(2)][BPh4] (6) (HMPA, hexamethylphosphoramide) was isolated from the reaction of [U(COT)(HMPA)(3)][BPh4](2) (3) with Ktmp. The cationic complexes 2 and 3 were recovered upon protonation of 4 and 6 with NEt3HBPh4. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01250-5