ammonium cadmium phosphate * H2O | 54892-04-5

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: ammonium cadmium phosphate * H2O
• 英文别名: ammonium cadmium phosphate monohydrate；Azanium;cadmium(2+);phosphate;hydrate
• CAS: 54892-04-5
• 化学式: Cd*H₂O*H₄N*O₄P
• 分子量: 243.435
• InChiKey: QNNWREPDEUGDCI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.28
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  154.25
• 氢给体数：
  1.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  ammonium cadmium phosphate * H2O 以100%的产率得到cadmium diphosphate
  参考文献：
  名称：

  Wijs, J. C. de, Recueil des Travaux Chimiques des Pays-Bas, 1943, vol. 62, p. 188 - 192

  摘要：

  DOI：
• 作为产物：
  描述：

  ammonium phosphate 、 镉 以 水 为溶剂， 生成 ammonium cadmium phosphate * H2O
  参考文献：
  名称：

  Miller; Page, Zeitschrift fur anorganische Chemie, 1901, vol. 28, p. 235 - 235

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 14.1, page 659 - 664
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 15.4, page 690 - 694
  作者：

  DOI：——

  日期：——
• A Comparative Study of the Synthesis of Calcium, Strontium, Barium, Cadmium, and Lead Apatites in Aqueous Solution
  作者：Natalie J. Flora、Keith W. Hamilton、Richard W. Schaeffer、Claude H. Yoder

  DOI：10.1081/sim-120030437

  日期：2004.3

  The aqueous syntheses of the hydroxy and halo apatites of calcium, strontium, barium, lead, and cadmium were explored. Because these cations represent the main group s- and p-tillers and a transition metal, they present different synthetic challenges. The alkaline earth cations and lead form hydrogen phosphates at slightly acidic and slightly basic conditions, the alkaline earths form the fluorides (MF2) in the preparation of the fluoroapatites with excess fluoride, and ammonia is required for the preparation of the cadmium apatites through decomplexation. A variety of reagents were utilized with most of the derivatives, but, in general, the source of the cation was its nitrate or halide, and the phosphate is best provided as ammonium hydrogen phosphate. The requirements for pH, heating, and reaction time were also explored. A number of literature syntheses for pure phase apatites could not be reproduced: calcium iodoapatite, strontium fluoroapatite, and cadmium hydroxyapatite. Several apatites were prepared for the first time in aqueous solution: barium fluoroapatite, lead bromoapatite, and cadmium chloroapatite. The relative ease of formation of the compounds is rationalized with arguments based upon lattice and hydration energies.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: MVol., 81, page 194 - 196
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cd: SVol., 15.1, page 666 - 666
  作者：

  DOI：——

  日期：——