((η(5)-C5Me5)(CO)2FeP=C(NMe2)Ph) | 285981-65-9

• 英文名称: ((η(5)-C5Me5)(CO)2FeP=C(NMe2)Ph)
• 英文别名: [(η(5)-C5Me5)(CO)2FeP=C(Ph)NMe2]
• CAS: 285981-65-9；303185-21-9
• 化学式: C₂₁H₂₆FeNO₂P
• 分子量: 411.264
• InChiKey: QJJMEMHGOXXRSO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  ((η(5)-C5Me5)(CO)2FeP=C(NMe2)Ph) 、 三氟甲烷磺酸甲酯 以 乙醚 为溶剂， 以83%的产率得到((η(5)-C5Me5)(CO)2FeP(Me)C(NMe2)Ph)SO3CF3
  参考文献：
  名称：

  10.1002/1521-3749(200009)626:9<1857::aid-zaac1857<3.0.co;2-0

  摘要：

  DOI：

  10.1002/1521-3749(200009)626:9<1857::aid-zaac1857<3.0.co;2-0
• 作为产物：
  描述：

  [Fe(pentamethylcyclopentadienyl)(CO)₂Cl] 、 Dimethyl-(phenyl-trimethylsilanylphosphanylidene-methyl)-amine 以 乙二醇二甲醚 、 正戊烷 为溶剂， 生成 ((η(5)-C5Me5)(CO)2FeP=C(NMe2)Ph)
  参考文献：
  名称：

  摘要：

  DOI：

  10.1002/(sici)1099-0682(200006)2000:6<1185::aid-ejic1185>3.3.co;2-y

文献信息

• Fumarodinitrile:  A Versatile Reagent in Phosphaalkene and Arsaalkene Chemistry
  作者：Lothar Weber、Stefan Kleinebekel、Lars Pumpenmeier、Hans-Georg Stammler、Beate Neumann

  DOI：10.1021/om010990c

  日期：2002.4.29

  Reaction of equimolar amounts of the ferriophosphaalkene Cp*(CO)(2)FeP=C(Ph)NMe2 (1a) and fumarodinitrile in diethyl ether afforded the ferriophosphetane CP*(CO)(2)FeP-CH(CN)-CH(CN)-C(Ph)NMe2 (2a). Analogously, Cp*(CO)(2)FeP=C(tBu)NMe2 (1b) was converted into Cp*(CO)(2)FeP-CH(CN)-CH(CN)-C(tBu)NMe2 (2b). Evidence for the cyclic structure of 2a,b in the crystal was provided by the X-ray structural analysis of 2a. Whereas the phosphetane ring of 2b is retained in solution, product 2a in CH2Cl2 solution underwent an isomerization to give the acyclic secondary ferriophosphane Cp*(CO)(2)Fe-P(H)-CH(CN)-C(CN)=C(Ph)NMe2 (3a) as a mixture of isomers. The ferriophosphane Cp*(CO)(2)FeP[CH(CN)-CH2CN]-[CH(CN)-C(CN)=C(tBu)NMe2] (5) was isolated in less than 1% yield from the reaction of 1b and the alkene. The reaction of ferrioarsaalkene Cp*(CO)(2)FeAs=C(Ph)NMe2 (6) and fumaronitrile gave rise to the formation of the ferrioarsetane Cp*(CO)(2)FeAsCH(CN)-CH-(CN)-C(Ph)NMe2 (7), which unlike 2a resists ring opening in solution.
• Azodicarbonsäureester und Diazoessigester als Reaktionspartner des Ferriophosphaalkens [Cp*(CO)2FeP=C(Ph)NMe2]
  作者：Lothar Weber、Stefan Kleinebekel、Hans-Georg Stammler、Anja Stammler

  DOI：10.1002/1521-3749(200205)628:4<810::aid-zaac810>3.0.co;2-d

  日期：2002.5

  Reaction of equimolar amounts of the ferriophosphaalkene [Cp*(CO)(2)FeP=C(Ph)NMe2] (1) and diethyl azodicarboxylate afforded the complex [(C5Me4CH2)(CO)(2)FeP<(CH(Ph)NMe2}-N(CO2Et)N=C(CO2Et)O)over bar> (3) as the result of a cheletropic [1 + 4] cycloaddition with subsequent transprotonation. The diazoacetates N-2=CHCO2R (8a:=tBu: 8b:Et) and 1 gave rise to the formation of the N-metallated 1,2,3-diazaphospholes [Cp*(CO)(2)FeN<(P=C(Ph)C(CO2R)=N])over bar> (11a, b). Compounds 3, 11a anti 11b were characterized by means of elemental analyses and spectroscopy (IR, H-1, C-13 H-1}. The molecular structure of 11a was determined by X-ray diffraction analysis.