Germane--yttrium (3/1) | 220690-36-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Germane--yttrium (3/1)
• 英文别名: germane;yttrium
• CAS: 220690-36-8
• 化学式: Ge₃Y
• 分子量: 306.676
• InChiKey: LOCQQFQQOSODPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.36
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  锗烷 、 氢化钇 以 neat (no solvent) 为溶剂， 生成 Germane--yttrium (3/1)
  参考文献：
  名称：

  Crystal structure of YGe3, YGe1.9 and a novel Y3Ge4 compound

  摘要：

  The crystal structure of the known YGe3 ('YGe3.5') and YGe1.9 ('YGe2') compounds and the novel Y3Ge4 compound have been studied by X-ray powder diffraction. It was found that crystal structure of YGe3 belongs to the DyGe3-type structure (a=4.0490(8) Angstrom, b=20.779(3) Angstrom, c=3.9184(8) Angstrom), YGe1.9 to the DyGe1.9-type structure (a=4.106(1) Angstrom, b=29.986(6) Angstrom, c=3.995(8) Angstrom) and Y3Ge4 to the Er3Ge4-type structure (a=4.052(1) Angstrom, b=10.649(2) Angstrom, c=14.265(3) Angstrom). (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0925-8388(98)00858-5

文献信息

• Superconductivity in YGe3
  作者：M.S. Wei、H.H. Sung、W.H. Lee

  DOI：10.1016/j.physc.2005.04.021

  日期：2005.8

  We report the discovery of a superconductor YGe3, Static magnetic susceptibility measurements show that the transition temperature T-c = 1.9-2.1 K (10-90% values). The zero resistivity temperature is attained below 2.2 K. Powder X-ray diffraction patterns indicate that this compound has the orthorhombic DyGe3-type structure with space group Cmcm. A refinement of the lattice parameters of the unit cell, determined by the method of least squares using the fifteen intense reflections for 2 theta < 60 degrees, reveals that the lattice parameters a = 4.0497(1) angstrom, b = 20.801(1) angstrom and e = 3.9174(1) angstrom for the compound YGe3. (c) 2005 Elsevier B.V. All rights reserved.