[(cyclopentadienyl)2Ti(N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolato)] | 1056899-85-4

• 英文名称: [(cyclopentadienyl)2Ti(N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolato)]
• 英文别名: [Cp2Ti(N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolato)]
• CAS: 1056899-85-4
• 化学式: C₁₉H₁₅NS₄Ti
• 分子量: 433.479
• InChiKey: JDEVTIZPZLYKKU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 3-phenylthiazole-2(3H)-thione 、 二氯二茂钛 在 lithium diisopropylamide 作用下， 以 四氢呋喃 为溶剂， 以30%的产率得到[(cyclopentadienyl)2Ti(N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolato)]
  参考文献：
  名称：

  Titanocene complexes of the N-methyl and N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolates and 4,5-diselenolate ligands

  摘要：

  Cp(2)Ti(dithiolene) and Cp(2)Ti(diselenolene) complexes containing the N-methyl-1,3-thiazoline-2-thione-4,5- dithiolate ligand (Me-thiazdt), the N-phenyl-1,3-thiazoline-2-thione-4,5-dithiolate ligand (Ph-thiazdt) and the N-methyl-1,3-thiazoline-2-thione-4,5-diselenolate ligand (Me-thiazds) have been synthesized. Three approaches have been developed in order to generate the dithiolene or the diselenolene ligands which were reacted with Cp(2)TiCl(2) to form the corresponding heteroleptic complexes. Their Xray crystal structures, UV-Vis absorption spectra as well as their redox properties, determined by cyclic voltammetry have been investigated and discussed. Variable-temperature (1)H NMR experiments have been performed in order to determine the activation energies of the chelate ring inversion. (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.05.021