Chromium--germane (3/1) | 12053-43-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Chromium--germane (3/1)
• 英文别名: chromium;germane
• CAS: 12053-43-9
• 化学式: Cr₃Ge
• 分子量: 228.578
• InChiKey: KBMZVYBMFFABKC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.46
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  (CO)5CrGeCl2(thf) 以 neat (no solvent) 为溶剂， 生成 锗烷 、 Chromium--germane (3/1)
  参考文献：
  名称：

  摘要：

  Thermal decomposition of the complexes (acac)(2)Ge(N-3)(2) (1), (acac)(2)GeCl2 (2), and (CO)(5)M=GeCl2(THF) (M = Cr (3), Mo (4), W (5)) was studied by differential scanning calorimetry and thermogravimetry. The phase compositions of the products of thermolysis of compounds 1-3 and 5 were deter-mined by X-ray phase analysis. Possible schemes of thermal decomposition of these compounds were proposed. The heat capacities of complexes 3-5 were studied in the temperature range 113-313 K. The structures of complexes I and 5 were established by X-ray diffraction analysis.

  DOI：

  10.1023/a:1026023814429

文献信息

• Esca and magnetic studies of the Cr-Ge system
  作者：M. Kolenda、J. Stoch、A. SzytuŁa

  DOI：10.1016/0304-8853(80)90532-6

  日期：1980.4
• Synthesis and characterization of Ge–Cr-based intermetallic compounds: GeCr3, GeCCr3, and GeNCr3
  作者：S. Lin、P. Tong、B.S. Wang、Y.N. Huang、W.H. Song、Y.P. Sun

  DOI：10.1016/j.jallcom.2013.09.086

  日期：2014.1

  We report the synthesis of GeCr3, GeCCr3, and GeNCr3 polycrystalline compounds, and present a systematic study of this series by the measurements of X-ray diffraction (XRD), magnetism, electrical/thermal transport, specific heat, and Hall coefficient. Good quality of our samples is verified by quite small value of residual resistivity and considerably large residual resistivity ratio. Based on the Rietveld refinement of XRD data, the crystallographic parameters are obtained, and, correspondingly, the sketches of crystal structure are plotted for all the samples. The ground states of GeCr3, GeCCr3, and GeNCr3 are paramagnetic/antiferromagnetic metal, and even a Fermi-liquid behavior is observed in electrical transport at low temperatures. Furthermore, the analysis of the thermal conductivity data suggests the electron thermal conductivity plays a major role in total thermal conductivity for GeCr3 at low temperatures, while the phonon thermal conductivity is dominant for GeCCr3 and GeNCr3 at high temperatures. The negative value of Seebeck coefficient and Hall coefficient indicate that the charge carriers are electron-type for GeCr3, GeCCr3, and GeNCr3. (C) 2013 Elsevier B. V. All rights reserved.