(2-Bromoethyl)acetophenethyl ether | 321901-45-5

• 英文名称: (2-Bromoethyl)acetophenethyl ether
• CAS: 321901-45-5
• 化学式: C₁₂H₁₅BrO₂
• 分子量: 271.154
• InChiKey: LQTNJKFTSVTCED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.84
• 重原子数：
  15.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  26.3
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  (2-Bromoethyl)acetophenethyl ether 在 aluminum isopropoxide 、 potassium hydrogensulfate 作用下， 以 异丙醇 、 乙醚 为溶剂， 反应 10.0h， 以42%的产率得到p-(2-Bromoethyl)styrylethyl ether
  参考文献：
  名称：

  Stamping of Monomeric SAMs as a Route to Structured Crystallization Templates: Patterned Titania Films

  摘要：

  Gold-coated glass slides have be patterned by using self-assembled monolayers (SAM) of alkane thiols. Through the use of a special thiol terminated with a styrene monomer, microstructures of 5 to 10 mum width and 70 Angstrom, height have been formed on the surface by graft polymerization of styrene. These patterned gold slides have then been used to template the precipitation of thin titania films from ethanolic solutions of titanium isopropoxide to create microstructured architectures in the film. Plasmon resonance spectra have established the presence of different steps in the process and have been used to follow the kinetics of the precipitation of titania on the surface. The structured TiO2 films have been characterized by scanning electron microscopy.

  DOI：

  10.1002/1521-3765(20001117)6:22<4149::aid-chem4149>3.0.co;2-p
• 作为产物：
  描述：

  2-(2-苯基乙氧基)乙醇 在 三氯化铝 、 氢溴酸 作用下， 以 二硫化碳 、 溶剂黄146 为溶剂， 反应 15.0h， 生成 (2-Bromoethyl)acetophenethyl ether
  参考文献：
  名称：

  Stamping of Monomeric SAMs as a Route to Structured Crystallization Templates: Patterned Titania Films

  摘要：

  Gold-coated glass slides have be patterned by using self-assembled monolayers (SAM) of alkane thiols. Through the use of a special thiol terminated with a styrene monomer, microstructures of 5 to 10 mum width and 70 Angstrom, height have been formed on the surface by graft polymerization of styrene. These patterned gold slides have then been used to template the precipitation of thin titania films from ethanolic solutions of titanium isopropoxide to create microstructured architectures in the film. Plasmon resonance spectra have established the presence of different steps in the process and have been used to follow the kinetics of the precipitation of titania on the surface. The structured TiO2 films have been characterized by scanning electron microscopy.

  DOI：

  10.1002/1521-3765(20001117)6:22<4149::aid-chem4149>3.0.co;2-p