bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0) | 190968-43-5

• 英文名称: bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)
• CAS: 190968-43-5
• 化学式: C₆₄H₆₈FeNP₃Pt
• 分子量: 1195.1
• InChiKey: CCCZQGATWVWUAN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙烯双(三苯基磷)铂 、 二氯膦二茂铁 、 2,4,6-三叔丁基-N-(三甲基甲硅烷基)苯胺 在 n-BuLi 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 以58.2%的产率得到bis(triphenylphosphino)-η(1)-P-ferrocenyl(tri-tertbutylphenyl)iminophosphinoplatinum(0)
  参考文献：
  名称：

  Synthesis and reactivity of P-ferrocenylalkylidenephosphanes and related iminophosphanes and diphosphenes

  摘要：

  P-Ferrocenyl-substituted alkylidenephosphanes have been prepared and characterized spectroscopically. Their ready conversion to the corresponding acylphosphanes and 1,2-diacyldiphosphanes, as well as a new type of phosphirene synthesis are presented. The X-ray structure of the tetraferrocenyl-substituted diacyldiphosphane has been investigated. Furthermore, P-ferrocenyl iminophosphanes and their complexation behaviour are described. Diferrocenyldiphosphene, which is known to be unstable, has been stabilized by complexation; this has been confirmed by NMR-spectroscopy and X-ray structure analysis.

  DOI：

  10.1016/s0022-328x(96)06482-0