Gold--lambda~2~-stannane (1/4) | 12044-91-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Gold--lambda~2~-stannane (1/4)
• 英文别名: gold;λ2-stannane
• CAS: 12044-91-6
• 化学式: AuSn₄
• 分子量: 671.806
• InChiKey: LAGIXDUKUBLDRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.67
• 重原子数：
  5.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Gold--lambda~2~-stannane (1/4) 、 1,2-二氰基苯 以 neat (no solvent, solid phase) 为溶剂， 生成 酞菁锡
  参考文献：
  名称：

  X-ray analysis of phthalocyanines formed in the reaction of AuCu and AuSn alloys with 1,2-dicyanobenzene

  摘要：

  X-ray investigations of the reactions of copper, tin and their alloys with gold, with 1,2-dicyanobenzene at 210-degrees-C have been performed. It was found that under the conditions used, gold does not take part in the reaction with 1,2-dicyanobenzene, but separates from the alloys. Copper and tin phthalocyanines are formed as the main products of the above reactions. The crystal structure of tin phthalocyanine (SnPC) has been determined. SnPc crystallizes in the triclinic system (a = 12.048(3) angstrom, b = 12.630(3) angstrom, c = 8.671(3) angstrom, alpha = 95.85(5)-degrees, beta = 95.10(5)-degrees, gamma = 68.25(5)-degrees), space group P1BAR, Z = 2. The refined structure with anisotropic temperature factors gave R = 0.041. The Sn atom is coordinated by four isoindole N atoms, the average Sn-N distance being 2.267(6) angstrom. The SnPc molecule is not planar. The Sn atom is 1.1286 angstrom out of the plane of the four coordinating N atoms.

  DOI：

  10.1016/0925-8388(92)90054-d
• 作为产物：
  描述：

  tin 、 金 以 melt 为溶剂， 生成 Gold--lambda~2~-stannane (1/4)
  参考文献：
  名称：

  Au1−xNixSn4 金属间合金的晶体结构

  摘要：

  摘要 涂有薄金层的镍通常用作电子封装中的金属化层。这种 Ni/Au 金属化在高于 Pb-Sn 焊料液相线的温度下与 Sn 形成合金。已经证明，在固态下对这些接头进行热处理，例如在 150°C 下，会导致在焊料界面形成 Au 1- x Ni x Sn 4 化合物。发现这些化合物对关节完整性有害。在这项工作中，进行了 Au 1- x Ni x Sn 4 合金的合成、显微结构分析和晶体结构测定。通过粉末和单晶 X 射线衍射、金相学、电子显微探针分析和热分析来检查合金。发现Ni原子取代AuSn 4 结构中的Au原子给出具有一般组成Au 1- x Ni x Sn 4 (x≤0.5)的化合物。标题化合物的结构被认为与 AuSn 4 相（PdSn 4 结构类型）同型，对称性从 Aba2 增加到 Ccca。使用 Rietveld 方法根据粉末数据对 x =0.25 和 0.50 的两种合金进行晶体结构细化，产生

  DOI：

  10.1016/s0925-8388(01)01780-7

文献信息

• Possibility of and conditions for the room temperature formation of compounds at the bulk metal/thin metal film interface
  作者：V. Simić、Ž. Marinković

  DOI：10.1016/0022-5088(83)90519-2

  日期：1983.12
• The crystal structure of AuNi2Sn4
  作者：Alexandra Neumann、A. Kjekshus、C. Rømming、E. Røst

  DOI：10.1016/0022-4596(95)80021-g

  日期：1995.10

  A hitherto unknown, virtually stoichiometric phase with composition AuNi2Sn4 has been identified in the Au-Ni-Sn system, and its structure has been determined by direct methods. The unit cell is rhombohedral (space group: R(3) over barm$) with dimensions a = 422.6(1) pm and c = 2656.6(4) pm in the hexagonal setting and a = 918.2(2) pm and alpha = 26.60(1)degrees in the rhombohedral setting. According to the hexagonal description Au is in 3b and Ni, Sn(I), and Sn(II) are in 6c with z = 0.40091(6), 029965(3), and 0.11204(3), respectively. AuNi2Sn4 proves to be isostructural with the mineral smythite (Fe3S4-s). The Fe3S4-s-type structure belongs to the NiAs-type family and certain aspects of the structural relationships are briefly discussed. (C) 1995 Academic Press,Inc.