(OC-6-23′)-[cobalt(III)(ceen)2(nitrite)(chlorido)]chloride | 1429222-61-6

• 英文名称: (OC-6-23′)-[cobalt(III)(ceen)2(nitrite)(chlorido)]chloride
• 英文别名: (OC-6-23′)-[cobalt(III)(ceen)₂(nitrite)(chlorido)]chloride；trans-[Co(III)(ceen)₂(NO₂)Cl]Cl
• CAS: 1429222-61-6
• 化学式: C₈H₂₂Cl₃CoN₅O₂*Cl
• 分子量: 421.1
• InChiKey: PPXNTUHAOHVOEJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三氟甲磺酸 、 (OC-6-23′)-[cobalt(III)(ceen)2(nitrite)(chlorido)]chloride 反应 0.75h， 生成 [Co(III)(ceen)₂(OTf)Cl](OTf)
  参考文献：
  名称：

  Synthesis of a nitrogen mustard ligand on a cobalt(III) metal centre

  摘要：

  N-(2-hydroxyethyl)ethane-1,2-diamine (heen) can be coordinated to give a single diastereoisomer of (OC-6-12'-[Co(heen)(2)(NO2)(2)](NO3), one of many possible isomers, which has been crystallographically characterised. The pendant alcohol groups can be then converted to the related alkyl halide. This represents a way of preparing a complex of a mustard ligand without having to prepare or handle the mustard itself. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.002
• 作为产物：
  描述：

  氯化亚砜 、 (OC-6-12')-[cobalt(III)(N-(2-hydroxyethyl)ethane-1,2-diamine)₂(nitrito)₂](NO₃)*monohydrate 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.5h， 以71%的产率得到(OC-6-23′)-[cobalt(III)(ceen)2(nitrite)(chlorido)]chloride
  参考文献：
  名称：

  Synthesis of a nitrogen mustard ligand on a cobalt(III) metal centre

  摘要：

  N-(2-hydroxyethyl)ethane-1,2-diamine (heen) can be coordinated to give a single diastereoisomer of (OC-6-12'-[Co(heen)(2)(NO2)(2)](NO3), one of many possible isomers, which has been crystallographically characterised. The pendant alcohol groups can be then converted to the related alkyl halide. This represents a way of preparing a complex of a mustard ligand without having to prepare or handle the mustard itself. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2012.08.002