Fe(2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl)(η2-C6H5CH2B(C6F5)3) | 474391-43-0

• 英文名称: Fe(2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl)(η2-C6H5CH2B(C6F5)3)
• 英文别名: [((Me)BDK)Fe(η2-PhCH2B(C6F5)3)]
• CAS: 474391-43-0
• 化学式: C₅₄H₄₈BF₁₅FeN₂
• 分子量: 1076.62
• InChiKey: SLSFGNDQNKHRBG-VCGBEGQOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氘代四氢呋喃 、 Fe(2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl)(η2-C6H5CH2B(C6F5)3) 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Neutral and cationic Fe(II) β-diketiminate complexes

  摘要：

  The three-coordinate, 12-valence electron complexes [((BDK)-B-Me)FeR] ((BDK)-B-Me = [HC(C(Me)NAr)(2)](-), Ar = 2,6-iPr(2)C(6)H(3), R = CH2Ph, CH2SiMe3) are reported as well as their reactivity towards Lewis bases. With perfluoroaryl borane and -borate type activators, the monoalkyls react to give alkyl-free paramagnetic cationic iron species counterbalanced by perfluorinated arylborate anions. The paramagnetic nature of the cations permits the observation of weak and dynamic interactions with these anions via F-19 NMR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.065
• 作为产物：
  描述：

  2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-2-pentene 在 CH₃(CH₂)3Li 作用下， 以 四氢呋喃 、 乙醚 、 正己烷 、 正戊烷 为溶剂， 生成 Fe(2,6-diisopropylphenyl)NC(CH3)CHC(CH3)N(2,6-diisopropylphenyl)(η2-C6H5CH2B(C6F5)3)
  参考文献：
  名称：

  Neutral and cationic Fe(II) β-diketiminate complexes

  摘要：

  The three-coordinate, 12-valence electron complexes [((BDK)-B-Me)FeR] ((BDK)-B-Me = [HC(C(Me)NAr)(2)](-), Ar = 2,6-iPr(2)C(6)H(3), R = CH2Ph, CH2SiMe3) are reported as well as their reactivity towards Lewis bases. With perfluoroaryl borane and -borate type activators, the monoalkyls react to give alkyl-free paramagnetic cationic iron species counterbalanced by perfluorinated arylborate anions. The paramagnetic nature of the cations permits the observation of weak and dynamic interactions with these anions via F-19 NMR spectroscopy. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.06.065

文献信息

• Benzyl anion abstraction from a (β-diiminato)Fe(ii) benzyl complexElectronic supplementary information (ESI) available: experimental data. See http://www.rsc.org/suppdata/cc/b2/b204454d/
  作者：Timo J.J. Sciarone、Auke Meetsma、Bart Hesssen、Jan H. Teuben

  DOI：10.1039/b204454d

  日期：2002.7.11

  The 3-coordinate 12 VE iron(II) benzyl complex [(nacnac)Fe(CH2Ph)] reacts with B(C6F5)3 to yield a paramagnetic contact ion pair with an η2-(o,m)-[PhCH2B(C6F5)3] anion, which was characterised by X-ray diffraction.

  3 配位 12 VE 铁(II)苄基络合物[(nacnac)Fe(CH2Ph)]与 B(C6F5)3 反应生成一个顺磁接触离子对，该离子对带有一个 Î-2-(o,m)-[PhCH2B( )3]阴离子，并通过 X 射线衍射对其进行了表征。