ruthenium(II) (norbanadiene)Cl2 | 48107-17-1

• 物质功能分类: 催化剂及助剂 - 贵金属催化剂
• 英文名称: ruthenium(II) (norbanadiene)Cl2
• 英文别名: {RuCl2(norbornadiene)}n；Ru(nbd)Cl₂；[η4-norbornadiene)RhCl2]n；RuCl2(2,5-norbornodiene)；[Ru(norbornadiene)Cl2]；[Ru(NBD)Cl2]
• CAS: 48107-17-1
• 化学式: C₇H₈Cl₂Ru
• 分子量: 264.117
• InChiKey: SPWWQFJJSFIUHB-HBJFUXGYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

安全信息

• WGK Germany：
  3

反应信息

• 作为反应物：
  描述：

  ruthenium(II) (norbanadiene)Cl2 在 Li{C₁₀H₈} 作用下， 以 四氢呋喃 为溶剂， 以5%的产率得到(η4-norbornadiene)(1,2,3,4,4a,8a-η-naphthalene)ruthenium(0)
  参考文献：
  名称：

  Crocker, Mark; Green, Michael; Howard, Judith A. K., Journal of the Chemical Society, Dalton Transactions

  摘要：

  DOI：
• 作为试剂：
  描述：

  1-丙烯基苯 、 2-吡啶基甲基甲酸酯 在 1,3-bis(1-adamantyl)benzimidazoliumchloride, 1,3-dicyclohexylbenzimidazolium chloride 、 ruthenium(II) (norbanadiene)Cl2 、 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 生成 pyridin-2-ylmethyl 2-phenylbutanoate 、 pyridin-2-ylmethyl 4-phenylbutanoate 、 pyridin-2-ylmethyl 2-methyl-3-phenylpropanoate
  参考文献：
  名称：

  烯烃的螯合辅助加氢酯化：新型钌催化剂体系和配体效应

  摘要：

  开发了新型的钌催化剂用于螯合辅助的分子间烯烃加氢酯化反应，该反应采用甲酸2-吡啶基甲基酯作为酯源。发现两类配体NHC和膦可促进反应以不同比率递送异构酯产物（直链与支链），从而允许进行配体引导的选择性加氢酯化。

  DOI：

  10.1021/ol500579n

文献信息

• The new Ru(NBD)Cl2(substituted-2,2′-biquinoline) complexes. Synthesis and characterization
  作者：Juan Guerrero、Liliana Farías、Luis Lemus、Africa Quintanilla、Alex Mena、Luis Cortez、Ricardo F. Baggio、María T. Garland

  DOI：10.1016/j.poly.2005.05.009

  日期：2006.1

  Abstract A new ruthenium complex series of type Ru(NBD)Cl2L (with L = 2,2′-biquinoline derivative) was prepared. Their spectroscopic properties were analysed by RMN 1H, UV–Vis and Infrared and their electrochemical potentials were obtained by cyclic voltammetry technique. The structure for a complex of this series was established by X-ray analysis. This structure shows a planarity distortion of biquinoline

  摘要制备了新的Ru（NBD）Cl2L型钌配合物系列（L = 2,2'-联喹啉衍生物）。用RMN 1H，UV-Vis和红外分析了它们的光谱性质，并通过循环伏安法获得了它们的电化学势。通过X射线分析确定了该系列复合物的结构。该结构显示出该复合物中联喹啉配体的平面度变形。通过复数序列的共面畸变度受2,2'-联喹啉配体上的3,3'-取代位置调节，并显示出与所观察到的光谱性质差异相关。
• Versatile <i>N,C,N</i> Coordination Behavior of a Monoanionic Aryldiamine Ligand in Ruthenium(II) Complexes:  Syntheses and Crystal Structures of [Ru^II{C₆H₃(CH₂NMe₂)₂-2,6}X(L)] (L = Norbornadiene, X = Cl, SO₃CF₃; L = PPh₃, X = I) and [Ru^II{C₆H₃(CH₂NMe₂)₂-2,6}(2,2‘:6‘,2‘‘-terpyridine)]Cl
  作者：Jean-Pascal Sutter、Stuart L. James、Pablo Steenwinkel、Thomas Karlen、David M. Grove、Nora Veldman、Wilberth J. J. Smeets、Anthony L. Spek、Gerard van Koten

  DOI：10.1021/om950700q

  日期：1996.2.6

  new ruthenium(II) complexes [RuC6H3(CH2NMe2)2-2,6}X(L)] (L = PPh3, X = Cl (2a), I (2b); L = norbornadiene (nbd), X = Cl (4), η1-OSO2CF3 (5)) and [RuC6H3(CH2NMe2)2-2,6}(2,2‘:6‘,2‘‘-terpyridine)]Cl (3). X-ray crystal structures of 2b and 3−5 have been determined, in which the N,C,N coordination geometry with respect to the metal center is found to differ considerably. In each complex the aryldiamine

  单阴离子配体[C 6 H 3（CH 2 NMe 2）2 -2,6] -可能是潜在的N，C，N键合体系，已用于合成一系列新的钌（II）配合物[Ru C 6 H 3（CH 2 NMe 2）2 -2,6} X（L）]（L = PPh 3，X = Cl（2a），I（2b）； L =降冰片二烯（nbd），X = Cl（4）中，η 1 -OSO 2 CF 3（5））和[孺C 6 ħ3（CH 2 NMe 2）2 -2,6}（2,2'：6'，2''-叔吡啶）] Cl（3）。的X射线晶体结构图2b和3 - 5，其中已经确定，N，C，N配位几何形状相对于金属中心被发现显着不同。在每一个复合物中的芳基二胺配体是terdentate，η 3 - N，C，N键合的为六个电子供体系统。然而，根据在钌（II）配位层的其它配体，该配体表明相当大的灵活性在采用协调的几何形状，其范围从子午在3通过pseudomerid
• Preparation and structure elucidation of novel organoruthenium amidinates bearing η4-diene ligands
  作者：Taizo Hayashida、Kazuma Miyazaki、Yoshitaka Yamaguchi、Hideo Nagashima

  DOI：10.1016/s0022-328x(01)01150-0

  日期：2001.9

  A series of novel ruthenium amidinate complexes bearing η4-cyclooctadiene (COD) or η4-norbornadiene (NBD) ligand was prepared, and their structures were elucidated by spectroscopy and crystallography. A disilver amidinate, Ag2μ2,η-PhNC(H)NPh}2, was treated with either (η4-COD)Ru(MeCN)2Cl2 or (η4-NBD)Ru(pyridine)2Cl2 to form the corresponding bisamidinate complex, (η4-COD)Ruη2-PhNC(H)NPh}2 (5a)

  一系列新颖钌脒基络合物轴承η的4 -cyclooctadiene（COD）或η 4 -norbornadiene（NBD）配位体制备，其结构分别通过光谱法和结晶学阐述。甲脒disilver，银2 μ 2，η-PhNC（H）NPh} 2，用任一（η处理4 -COD）的Ru（MeCN中）2氯2或（η 4 -NBD）的Ru（吡啶）2 CL 2以形成相应的bisamidinate络合物，（η 4 -COD）茹η 2 -PhNC（H）NPh} 2（图5a）或（η 4 -NBD）茹η 2-PhNC（H）= NPh} 2（5a），分别具有中等至良好的产量。可替代地，（η 4 -COD）茹η 2 -我PRNC（Me）中N我镨} 2（图5b）或（η 4 -NBD）茹η 2 -我PRNC（Me）中N我镨} 2（图5b '）通过的反应合成[（η 4 -COD）的RuCl 2 ] ñ或（η 4 -NBD）的Ru（吡啶）2氯2与Li
• Synthesis and structural characterization of ruthenium(II) complexes of histidine and methionine derivatives
  作者：W.S. Sheldrick、R. Exner

  DOI：10.1016/s0020-1693(00)83844-x

  日期：1992.5

  The L-histidinate complexes [RuCl(L-his)(diene)] (diene = nbd (1), cod (2)) may be prepared by reaction of [RUCl2(dien)]n with L-hisH in aqueous solution at reflux. An X-ray analysis of 1 established that the histidinate anion is present as a facial tridentate ligand with the amino nitrogen sited trans to chlorine. Reaction of [RuCl2(PPh3)3] with D,L-histidine in methanol at reflux leads to the formation of [RuCl(D,L-his)(PPh3)2] (3), which also contains a facially coordinated tridentate histidinate ligand (X-ray analysis). In contrast to 1, the coordinating imidazole nitrogen is now in trans position to the chlorine atom. The complexes [RuCl2(L-hisme)(PPh3)2] (4), [RuCl(D,L-met)(PPh3)2] . CH3OH (5) and [RuCl(L-metme)2(PPh3)]Cl . PPh3 (6) were characterized by spectroscopic studies and in the case of 6 by an X-ray structural analysis. In the latter bis-chelate complex the thioether sulfur atoms adopt coordination sites trans to an amino nitrogen and the PPh3 phosphorus, respectively. In aqueous or methanolic solution 6 is readily oxidized by traces of oxygen. The analogous ruthenium(III) reaction product for L-methionine ethyl ester (L-metet), [RuCl3(L-metet)(PPh3)] (7) was characterized by X-ray analysis. The electrochemistry of 4 and 7 has been studied.
• Structures, spectroscopy, and a mechanism of formation of linked-norbornadiene complexes of ruthenium(II). Interaction of ruthenium(II) with alicyclic hydrogen atoms
  作者：Kenji Itoh、Noriaki Oshima、Geoffrey B. Jameson、Huntley C. Lewis、James A. Ibers

  DOI：10.1021/ja00401a018

  日期：1981.6