Gold--lambda~2~-stannane (1/2) | 12256-54-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 各种混合金属/非金属
• 英文名称: Gold--lambda~2~-stannane (1/2)
• 英文别名: gold;λ2-stannane
• CAS: 12256-54-1
• 化学式: AuSn₂
• 分子量: 434.386
• InChiKey: BSJMRGPPKRQTFE-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tin 、 金 以 melt 为溶剂， 生成 Gold--lambda~2~-stannane (1/2)
  参考文献：
  名称：

  Biltz, W.; Rohlffs, G.; Vogel, H. U. v., Zeitschrift fur anorganische Chemie, 1934, vol. 220, p. 113 - 141

  摘要：

  DOI：

文献信息

• Nilges, Tom; Kersting, Marcel; Pfeifer, Thorben, Journal of Solid State Chemistry, 2008, vol. 181, p. 1707 - 1711
  作者：Nilges, Tom、Kersting, Marcel、Pfeifer, Thorben

  DOI：——

  日期：——
• Possibility of and conditions for the room temperature formation of compounds at the bulk metal/thin metal film interface
  作者：V. Simić、Ž. Marinković

  DOI：10.1016/0022-5088(83)90519-2

  日期：1983.12
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Au: MVol.3, 15.1, page 832 - 853
  作者：

  DOI：——

  日期：——
• The crystal structure of AuNi2Sn4
  作者：Alexandra Neumann、A. Kjekshus、C. Rømming、E. Røst

  DOI：10.1016/0022-4596(95)80021-g

  日期：1995.10

  A hitherto unknown, virtually stoichiometric phase with composition AuNi2Sn4 has been identified in the Au-Ni-Sn system, and its structure has been determined by direct methods. The unit cell is rhombohedral (space group: R(3) over barm$) with dimensions a = 422.6(1) pm and c = 2656.6(4) pm in the hexagonal setting and a = 918.2(2) pm and alpha = 26.60(1)degrees in the rhombohedral setting. According to the hexagonal description Au is in 3b and Ni, Sn(I), and Sn(II) are in 6c with z = 0.40091(6), 029965(3), and 0.11204(3), respectively. AuNi2Sn4 proves to be isostructural with the mineral smythite (Fe3S4-s). The Fe3S4-s-type structure belongs to the NiAs-type family and certain aspects of the structural relationships are briefly discussed. (C) 1995 Academic Press,Inc.