[(cyclooctadiene)(trimethylsilylbenzene)]ruthenium(0) | 187108-05-0

• 英文名称: [(cyclooctadiene)(trimethylsilylbenzene)]ruthenium(0)
• CAS: 187108-05-0
• 化学式: C₁₇H₂₆RuSi
• 分子量: 359.549
• InChiKey: GBYAOWZPSNYHBW-GHDUESPLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η6-naphthalene)(η4-1,5-cyclooctadiene)ruthenium(0) 、 三甲基苯基硅烷 以 四氢呋喃 、 乙腈 为溶剂， 以90%的产率得到[(cyclooctadiene)(trimethylsilylbenzene)]ruthenium(0)
  参考文献：
  名称：

  A Specific Route to Enantiomerically Pure Asymmetric (η ⁶ ‐Arene)(η ⁴ ‐1,5‐cyclooctadiene)Ru(0) Complexes

  摘要：

  AbstractChiral or achiral (arene)(COD)Ru complexes can be made by replacing the η6‐ligands of (η4‐1,5‐COD)(η6‐1,3,5‐cyclooctatriene)Ru (1) or (η4‐1,5‐COD)(η6‐naphthalene)Ru (2) by a suitable arene. This well known reaction has been extended to mono‐ and dibromoarenes and we report a novel route to substituted (arene)(COD)Ru species, utilizing (bromoarene)‐(COD)Ru as starting materials. These facilitate a rapid bromine‐lithium exchange reaction with nBuLi at low temperatures and the lithiated species react readily with alkyl chloroformates as electrophiles. By using chiral electrophiles [alkyl = (‐)‐menthyl] enantiomerically pure or diastereomeric complexes containing CO2R* groups are formed, depending on the symmetry of the original complex. A diastereomeric 1:1 mixture was separated by recrystallization. All (arene)‐(COD)Ru complexes tested so far are useful as catalysts for the hydrogenation of simple alkenes at room temperature.

  DOI：

  10.1002/cber.19971300121
• 作为试剂：
  描述：

  1-己烯 在 [(cyclooctadiene)(trimethylsilylbenzene)]ruthenium(0) 氢气 作用下， 以 四氢呋喃 为溶剂， 反应 15.0h， 生成 正己烷
  参考文献：
  名称：

  A Specific Route to Enantiomerically Pure Asymmetric (η ⁶ ‐Arene)(η ⁴ ‐1,5‐cyclooctadiene)Ru(0) Complexes

  摘要：

  AbstractChiral or achiral (arene)(COD)Ru complexes can be made by replacing the η6‐ligands of (η4‐1,5‐COD)(η6‐1,3,5‐cyclooctatriene)Ru (1) or (η4‐1,5‐COD)(η6‐naphthalene)Ru (2) by a suitable arene. This well known reaction has been extended to mono‐ and dibromoarenes and we report a novel route to substituted (arene)(COD)Ru species, utilizing (bromoarene)‐(COD)Ru as starting materials. These facilitate a rapid bromine‐lithium exchange reaction with nBuLi at low temperatures and the lithiated species react readily with alkyl chloroformates as electrophiles. By using chiral electrophiles [alkyl = (‐)‐menthyl] enantiomerically pure or diastereomeric complexes containing CO2R* groups are formed, depending on the symmetry of the original complex. A diastereomeric 1:1 mixture was separated by recrystallization. All (arene)‐(COD)Ru complexes tested so far are useful as catalysts for the hydrogenation of simple alkenes at room temperature.

  DOI：

  10.1002/cber.19971300121