Cp(CO)2FeMgCl | 533903-76-3

• 英文名称: Cp(CO)2FeMgCl
• CAS: 533903-76-3
• 化学式: C₇H₅ClFeMgO₂
• 分子量: 236.72
• InChiKey: TVQHTNOZUAFCMO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  三羰基环戊基氯化钼 、 Cp(CO)2FeMgCl 以 N,N-二甲基甲酰胺 为溶剂， 以71%的产率得到
  参考文献：
  名称：

  摘要：

  Oxidation of magnesium with dicarbonyl(cyclopentadienyl)iron(II) chloride in dimethylformamide gives rise to eta(5)-C5H5Fe(CO)(2)MgCl. Kinetic regularities of the process were determined. Thermodynamic parameters of adsorption of the reagents on the metal,surface were calculated.

  DOI：

  10.1023/a:1023358311713
• 作为产物：
  描述：

  二氯四吡啶铁(II) 、 magnesium 以 N,N-二甲基甲酰胺 、 xylene 为溶剂， 生成 Cp(CO)2FeMgCl
  参考文献：
  名称：

  摘要：

  Oxidation of magnesium with dicarbonyl(cyclopentadienyl)iron(II) chloride in dimethylformamide gives rise to eta(5)-C5H5Fe(CO)(2)MgCl. Kinetic regularities of the process were determined. Thermodynamic parameters of adsorption of the reagents on the metal,surface were calculated.

  DOI：

  10.1023/a:1023358311713

文献信息

• Synthesis of Bis( ⁵-cyclopentadienyldicarbonyliron)stannane Dichloride by Direct Oxidation of Tin and Reaction of This Compound and Its Analogs with Magnesium
  作者：S. V. Maslennikov、M. V. Tsarev、I. V. Spirina、A. V. Lado、V. P. Maslennikov、A. A. Usanov

  DOI：10.1023/b:rugc.0000045872.42657.fd

  日期：2004.7

  A procedure was developed for preparing [Cp(CO)(2)Fe](2)SnCl2 by direct oxidation of tin with eta5-cyclopentadienyldicarbonyliron chloride in polar solvents. The reaction kinetics was studied, and its scheme was suggested. Products of the reaction of magnesium with compounds R2SnCl2 [R = CP(CO)(3)Mo, Cp(CO)(3)W, Cp(CO)(2)Fe] were identified. The reaction mechanism was discussed.