Cs[nido-7-Me-7,8-C2B9H11] | 89462-09-9

• 英文名称: Cs[nido-7-Me-7,8-C2B9H11]
• 英文别名: Cs[7-methyl-7,8-C2B9H11]
• CAS: 89462-09-9
• 化学式: C₃H₁₄B₉*Cs
• 分子量: 280.349
• InChiKey: PGNVYEHVQVUZDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Cs[nido-7-Me-7,8-C2B9H11] 、 (PPh₂Me)₂NiCl₂ 在 potassium tert-butylate 作用下， 以 四氢呋喃 为溶剂， 以57 %的产率得到3,3-(MePh₂P)2-1-Me-closo-3,1,2-NiC₂B₉H₁₀
  参考文献：
  名称：

  Interligand Interactions in Half-Sandwich Nickelacarboranes with Phosphine Ligands: Away from Skeletal Rearrangements

  摘要：

  Reactions of nickel(II) phosphine complexes [(dppe)NiCl2], [(MePh2P)2NiCl2] and [(Ph3P)2NiCl2] with C-substituted nido-carboranes [7-R-nido-7,8-C2B9H11]− (R = Me, Ph, C(NHCy)2+) were studied. The reactions with [(dppe)NiCl2] lead to the corresponding nickelacarboranes 3,3-(dppe)-1-R-closo-3,1,2-NiC2B9H10 with absent or negligible steric interactions between the ligands. The reactions of [(MePh2P)2NiCl2]

  DOI：

  10.1021/acs.organomet.2c00598
• 作为产物：
  描述：

  1-methyl-ortho-carborane 、 cesium fluoride 以 乙醇 为溶剂， 以98 %的产率得到Cs[nido-7-Me-7,8-C2B9H11]
  参考文献：
  名称：

  Interligand Interactions in Half-Sandwich Nickelacarboranes with Phosphine Ligands: Away from Skeletal Rearrangements

  摘要：

  Reactions of nickel(II) phosphine complexes [(dppe)NiCl2], [(MePh2P)2NiCl2] and [(Ph3P)2NiCl2] with C-substituted nido-carboranes [7-R-nido-7,8-C2B9H11]− (R = Me, Ph, C(NHCy)2+) were studied. The reactions with [(dppe)NiCl2] lead to the corresponding nickelacarboranes 3,3-(dppe)-1-R-closo-3,1,2-NiC2B9H10 with absent or negligible steric interactions between the ligands. The reactions of [(MePh2P)2NiCl2]

  DOI：

  10.1021/acs.organomet.2c00598

文献信息

• Facile and Mild Deboronation of <i>o</i>-Carboranes Using Cesium Fluoride
  作者：Jeongsoo Yoo、Jeong-Wook Hwang、Youngkyu Do

  DOI：10.1021/ic000768k

  日期：2001.1.1

  The o-carborane and substituted derivatives were degraded effectively using cesium fluoride in ethanol under reflux conditions, producing cesium salts of nido monoanions directly in high yield.
• Metallacarboranes in catalysis. 5. Interconversion of closo-bis(phosphine)hydridorhodacarboranes by rhodium transfer between .eta.-nido-carborane anions
  作者：Judith A. Long、Todd B. Marder、M. Frederick Hawthorne

  DOI：10.1021/ja00322a041

  日期：1984.5