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sodium perchlorate monohydrate | 7791-07-3

中文名称
——
中文别名
——
英文名称
sodium perchlorate monohydrate
英文别名
sodium perchlorate hydrate;sodium perchlorate;sodium;perchlorate;hydrate
sodium perchlorate monohydrate化学式
CAS
7791-07-3
化学式
ClO4*H2O*Na
mdl
——
分子量
140.456
InChiKey
IXGNPUSUVRTQGW-UHFFFAOYSA-M
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 熔点:
    130 °C
  • 密度:
    2,02 g/cm3
  • 溶解度:
    H2O:100 mg/mL,澄清,无色
  • 稳定性/保质期:
    避免接触还原剂、有机材料、金属粉末以及水分或潮湿环境。该物质易溶于水,在15℃时,100cm³水中可溶解209g;而在50℃时,100cm³水中可溶解284g。它还能溶解在乙醇中,密度为2.02g/cm³。此外,该物质会在浓硫酸中干燥或加热到50℃时失去结晶水。

计算性质

  • 辛醇/水分配系数(LogP):
    -8.58
  • 重原子数:
    7
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    75.3
  • 氢给体数:
    1
  • 氢受体数:
    5

ADMET

毒理性
  • 副作用
高铁血红蛋白血症 - 血液中高铁血红蛋白含量增加;该化合物被归类为继发性毒性效应。
Methemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

安全信息

  • TSCA:
    Yes
  • 危险等级:
    5.1
  • 危险品标志:
    O,Xi,Xn
  • 安全说明:
    S13,S17,S22,S26,S27,S36/37/39
  • 危险类别码:
    R9
  • WGK Germany:
    3
  • 海关编码:
    2829199000
  • 危险品运输编号:
    UN 1502 5.1/PG 2
  • 危险类别:
    5.1
  • RTECS号:
    SC9850000
  • 包装等级:
    II
  • 危险标志:
    GHS03,GHS07
  • 危险性描述:
    H271,H302
  • 危险性防范说明:
    P220

SDS

SDS:725707ffc4411412b8c56e373a11a590
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Name: Sodium Perchlorate Monohydrate P.A. Material Safety Data Sheet
Synonym: None known
CAS: 7791-07-3
Section 1 - Chemical Product MSDS Name:Sodium Perchlorate Monohydrate P.A. Material Safety Data Sheet
Synonym:None known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
7791-07-3 Sodium Perchlorate Monohydrate ca 100 unlisted
Hazard Symbols: XN O
Risk Phrases: 22 9

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful if swallowed. Explosive when mixed with combustible material.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. May cause permanent corneal opacification.
Skin:
May cause severe irritation and possible burns.
Ingestion:
May cause burns to the gastrointestinal tract. May cause nausea, vomiting, and diarrhea, possibly with blood.
Inhalation:
Causes respiratory tract irritation. May cause acute pulmonary edema, asphyxia, chemical pneumonitis, and upper airway obstruction caused by edema.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may be delayed.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water with caution and in flooding amounts. Some oxidizers may react explosively with hydrocarbons(fuel). May accelerate burning if involved in a fire. Containers may explode when heated.
Extinguishing Media:
Use water only! Contact professional fire-fighters immediately. For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY. For large fires flood fire with water from a distance.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Do not use combustible materials such as paper towels to clean up spill.

Section 7 - HANDLING and STORAGE
Handling:
Use with adequate ventilation. Minimize dust generation and accumulation. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed.
Avoid contact with clothing and other combustible materials. Do not get on skin or in eyes. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry place. Keep away from reducing agents.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Appearance: colorless or white
Odor: odorless
pH: 6-8 (5% solution)
Vapor Pressure: Not applicable.
Viscosity: Not applicable.
Boiling Point: 482 deg F
Freezing/Melting Point: 266 deg F
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 482 deg F
Solubility in water: 209% @ 15 C
Specific Gravity/Density: 2.02
Molecular Formula: NaO4Cl.H20
Molecular Weight: 140

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation, combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Chlorine, oxygen.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 7791-07-3: SC9850000 LD50/LC50:
Not available.
Carcinogenicity:
Sodium Perchlorate Monohydrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN O
Risk Phrases:
R 22 Harmful if swallowed.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding
stuffs.
S 22 Do not breathe dust.
S 27 Take off immediately all contaminated clothing.
WGK (Water Danger/Protection)
CAS# 7791-07-3: No information available.
United Kingdom Occupational Exposure Limits
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 7791-07-3 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
US FEDERAL
TSCA
CAS# 7791-07-3 is not on the TSCA Inventory. It is a hydrate and
exempt from TSCA Inventory requirements (40CFR720.3(u)(2)).


SECTION 16 - ADDITIONAL INFORMATION
N/A



制备方法与用途

水中溶解度(g/100ml)在不同温度(℃)时每100毫升水中的溶解克数如下:

  • 167g/0℃
  • 183g/10℃
  • 201g/20℃
  • 222g/30℃
  • 245g/40℃
  • 288g/60℃
  • 306g/80℃
  • 329g/100℃

用途: 主要用于制造高氯酸或其他高氯酸盐,还应用于火药工业。

反应信息

  • 作为反应物:
    描述:
    sodium perchlorate monohydrate 以 neat (no solvent) 为溶剂, 生成 sodium perchlorate
    参考文献:
    名称:
    无机高氯酸盐表征中的35Cl和(37)Cl魔角旋转NMR光谱。
    摘要:
    从(35)Cl幻角纺丝(MAS)中确定了一系列无机高氯酸盐的35Cl四极偶合常数(C(Q)),不对称参数(eta(Q))和各向同性化学位移(delta(iso)) )在14.1 T的NMR光谱。获得了示例性的(37)Cl MAS NMR光谱,并对某些样品进行了分析。对于四极偶合小于约1 MHz的高氯酸根阴离子,(35)Cl /(37)Cl NMR参数最精确地由卫星过渡观察到的自旋边带的全部流形确定,而中心过渡的线形分析为用于较大的四极耦合。高氯酸根阴离子的环境最好通过四极偶合参数(例如,C(Q)范围从0.3到3.0 MHz)来表征,而各向同性(35)Cl化学位移的分散度很小(1029 ppm <δ(iso)<1049 ppm)。由于四极偶合参数的变化,在相变,水合反应和混合相组成的研究中,(35)Cl MAS NMR可方便地用于鉴定高氯酸盐的无水和水合相。研究的高氯酸盐包括无水KClO(4
    DOI:
    10.1021/ic9811650
  • 作为产物:
    描述:
    sodium perchlorate 以 为溶剂, 生成 sodium perchlorate monohydrate
    参考文献:
    名称:
    Schuhmacher, J. C., R. E. Kirk, D. F. Othmer: Encyclopedia of Chemical Technology, Vol. 3, New York 1949, p. 723
    摘要:
    DOI:
  • 作为试剂:
    描述:
    五氟苯酚Langlois reagentsodium perchlorate monohydrate 作用下, 以 乙腈 为溶剂, 以75%的产率得到octafluoroanisole
    参考文献:
    名称:
    缺电子酚的电化学O-三氟甲基化
    摘要:
    提出了一种通过电化学合成从相应的酚类制备缺电子芳基三氟甲基醚 (ArOCF 3 )的简单且可持续的一步策略。三氟甲烷亚磺酸盐(Langlois 试剂)的阳极氧化导致带有氟、氯、溴和腈取代基的苯酚衍生物在温和条件下直接O-三氟甲基化,产率高达 75%,克级。这种电化学协议为原本难以接近的一类分子提供了一种经济和绿色的合成,而无需昂贵或有毒的试剂、氧化剂或金属催化剂。
    DOI:
    10.1016/j.elecom.2021.107165
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文献信息

  • Preparation and reactions of 2-pyridylplatinum(II) complexes [PtCl(C5H4N-C2)(L)2] (L = tertiary phosphine) Compounds with a markedly nucleophilic pyridine nitrogen atom
    作者:Bruno Crociani、Francesca Di Blanca、Amalia Giovenco、Adriano Berton、Roberta Bertani
    DOI:10.1016/0022-328x(89)85390-2
    日期:1989.2
    reaction suggests that PPh3 transfer occurs in a binuclear platinum/palladium intermediate with a bridging 2-pyridyl ligand, and leads initially to a chloride-bridged species [Pt(μ-Cl)(C5H4-N-C2)(PPh3)]2, which then rearranges to the more stable compound IV. Complexes I and II are readly N-protonated by HCl or HClO4 to give the cationic derivatives [PtCl(C5H5N-C2)(PPh3)2]+ and [PtCl(C5H5N-C2)(dppe)]+. In
    通过将2-氯吡啶氧化加成到[Pt(PPh 3)4 ]中,可以高产率地制备2-吡啶基复合物反式-[PtCl(C 5 H 4 N- C 2)(PPh 3)2 ](I)。。I与1,2-双(二苯基膦基)乙烷的反应产生顺式衍生物[PtCl(C 4 5 H 4 N- C 2)(dppe)](II)。在极性溶剂中,后者重排的双核阳离子络合物[PT(μ-C 5 H ^ 4 N- Ç 2,Ñ)(DPPE)] 2Cl 2。的我与反应[的PdCl(η 3 -2-MEC 3 ħ 4)] 2(1 / 0.5摩尔比),得到产物[氯铂酸(μ-C 5 H ^ 4 N- Ç 2,Ñ)(PPH 3) ] 2(IV)和[的PdCl(η 3 -2-MEC 3 ħ 4)(PPH 3)]。反应的31 P NMR监测表明,PPh 3转移发生在具有桥联2-吡啶基配体的双核铂/钯中间体中,并最初导致了氯离子桥连的物质[Pt(μ-Cl)(C
  • Rhodium(III) complexes containing unidentate amines
    作者:Steve P. Dagnall、Martin P. Hancock、Brian T. Heaton、D. Huw Vaughan
    DOI:10.1039/dt9770001111
    日期:——
    constants and activation parameters for the substitution of chloride by bromide in [Rh(NRH2)5Cl]2+ and trans-[Rh(NRH2)4Cl2]+(R = Me, Et, or Prn) have been determined and are compared with data on related complexes of RhIII, CoIII, and CrIII.
    便捷合成[Rh(NRH 2)5 X] 2+(R = Me,Et,Pr n,Bu n或Bu i ; X = Cl或Br),反式-[Rh(NR'H 2)4 Cl 2 ] +(R'= PR我,环己基,或pH),和反式- [铑(PYR)4氯2 ] +(PYR =吡咯烷)的报告和铑[Rh(NRH 2)5 CL] 2+被示出成为合成反式-[Rh(NRH 2)的方便原料4 Cl 2 ] +。报告了极谱半波降低电势以及物理和光谱性质。反式-[Rh(NMeH 2) 4 Cl 2 ] +中氨基质子的交换速率以及[Rh(NRH 2) 5 Cl] 2+和反式中溴化物取代氯的速率常数和活化参数-[Rh(NRH 2) 4 Cl 2 ] +(R = Me,Et或Pr n)已确定,并与Rh相关配合物的数据进行比较III,Co III和Cr III。
  • Cobalt cage complexes as mediators of protein electron transfer
    作者:Felix M. C. He、Paul V. Bernhardt
    DOI:10.1007/s00775-016-1427-y
    日期:2017.7
    AbstractA selection of cobalt (III)/(II) macrobicyclic ‘sarcophagine’ (sar) cage complexes with N3S3 mixed donor sets but differing in a single apical substituent has been chosen to span a redox potential range of +150 to −150 mV vs the normal hydrogen electrode and thus acts as redox buffers in protein spectroelectrochemistry and redox potentiometry. The cobalt(III) cage complexes are all based on the
    摘要已选择具有N 3 S 3混合供体组但在单个顶部取代基上有所不同的钴(III)/(II)大双环'sarcophagine'(sar)笼状配合物,其氧化还原电位范围为+150至-150 mV与正常氢电极相比,因此在蛋白质光谱电化学和氧化还原电位测定中充当氧化还原缓冲液。钴(III)笼络合物均基于相同的母体结构[Co(X MeN 3 S 3 sar)] 3+,其中可变的顶部取代基X为–NO 2,–Cl,–OH,–NH 2,或–NMe + 3 ,甲基位于相反的顶端位置。报告了该系列中选定成员的X射线晶体结构。顶端取代基X的变化使Co III / II氧化还原电势可以通过官能团的感应作用在200 mV以上的范围内调节。氧化还原电势的pH依赖性使得可以确定某些官能团的p K a值。该配合物已成功地用作电子转移介质,用于各种血红素蛋白的光谱电化学研究。 图形概要
  • Hypoglycemic
    申请人:Merrell Dow Pharmaceuticals Inc.
    公开号:US04533677A1
    公开(公告)日:1985-08-06
    N-(3-Dialkylamino-2-propenylidene)-N-alkylalkanaminium salts substituted in the 2-position with an ether or thioether and having the formula ##STR1## are active as hypoglycemic agents.
    N-(3-二烷氨基-2-丙烯基亚甲基)-N-烷基烷基胺盐在2位被醚或硫醚取代,并具有以下结构式的化学式##STR1##,作为降血糖药物具有活性。
  • Tetradentate selenium ligand as a building block for homodinuclear complexes of Pd(ii) and Ru(ii) having seven membered rings or bis-pincer coordination mode: high catalytic activity of Pd-complexes for Heck reaction
    作者:Dipanwita Das、Pradhumn Singh、Monika Singh、Ajai Kumar Singh
    DOI:10.1039/c0dt00561d
    日期:——
    coordination mode. The geometry around Pd in 1 or 2 is close to square planar whereas in 3, Ru has pseudo-octahedral half sandwich “Piano–Stool” geometry. The Pd–Se bond distances are in the ranges 2.4004(9)–2.4627(14) Å and follow the order 1 > 2, whereas Ru–Se bond lengths are between 2.4945(16) and 2.5157(17) Å. The 1 and 2 have been found efficient catalysts for Heck reaction of aryl halides with styrene
    1,2,4,5-四(苯并硒甲基)苯(大号)已经通过反应合成的原位生成的硒化钾−与1,2,4,5-四(溴甲基)苯在N 2气氛中。它的第一个双金属络合物和双-钳形络合物具有的组合物[(η 3 -C 3 H ^ 5)2的Pd 2(大号)] [CLO 4 ] 2(1)[钯2(C 5 H ^ 5 N)2(大号)] [BF 4 ] 2(2)和[(η 6 -C 6 H ^ 6)2的Ru 2(大号)氯2 ] [PF 6] 2(3)已经通过反应而合成的大号与[将Pd(η 3 -C 3 H ^ 5)CL] 2,[加入Pd(CH 3 CN)4 ] [BF 4 ] 2和[(η 6 -C 6 H ^ 6)2 RuCl 2 ] 2。配体L及其所有三个配合物的结构已经通过X射线晶体学确定。在1和3中,配体L与两个有机金属物种形成7个螯合环,而在2个中则以双-钳位配位模式连接。周围的几何钯在1或2中,它接近于正方形平面,
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