摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词
历史搜索
    热门化合物HOT
    • 喹啉
    • 水杨醛
    • 二溴甲烷
    • 谷胱甘肽
    • L-乳酸
    • 苯巴比妥
    • 辣椒碱
    • 非那明
    • 百草枯
    • 联苯烯
    首页 分子通 (-)-orientalinone

    (-)-orientalinone | 2689-17-0

    分子结构分类

    有机化合物 - 生物碱及其衍生物 - 阿朴啡原
    中文名称
    ——
    中文别名
    ——
    英文名称
    (-)-orientalinone
    英文别名
    (2S,4S)-11-hydroxy-2',10-dimethoxy-5-methylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one
    (-)-orientalinone化学式
    CAS
    2689-17-0
    化学式
    C19H21NO4
    mdl
    ——
    分子量
    327.38
    InChiKey
    RICRDZJWIPYDGM-HXPMCKFVSA-N
    BEILSTEIN
    ——
    EINECS
    ——
    • 物化性质
    • 计算性质
    • ADMET
    • 安全信息
    • SDS
    • 制备方法与用途
    • 上下游信息
    • 反应信息
    • 文献信息
    • 表征谱图
    • 同类化合物
    • 相关功能分类
    • 相关结构分类

    物化性质

    • 熔点：
      183-184 °C
    • 沸点：
      515.4±50.0 °C(Predicted)
    • 密度：
      1.33±0.1 g/cm3(Predicted)

    计算性质

    • 辛醇/水分配系数(LogP)：
      2.4
    • 重原子数：
      24
    • 可旋转键数：
      2
    • 环数：
      4.0
    • sp3杂化的碳原子比例：
      0.42
    • 拓扑面积：
      59
    • 氢给体数：
      1
    • 氢受体数：
      5

    上下游信息

    • 下游产品
      中文名称 英文名称 CAS号 化学式 分子量

    反应信息

    • 作为反应物：
      描述：
      (-)-orientalinone 以 甲醇 为溶剂， 反应 9.0h， 以3%的产率得到2-methoxy-6-methyl-5,6,6a,7-tetrahydro-4H-dibenzo[de,g]quinoline-1,11-diol
      参考文献：
      名称：
      The photolysis of proaporphines
      摘要：
      DOI：
      10.1016/s0040-4039(00)84405-6
    点击查看最新优质反应信息

    文献信息

    • New proaporphine alkaloids from roemeria hybrida
      作者：Belkis Gözler、Tekant Gözler、I. Ergün Mete、Alan J. Freyer、Hélène Guinaudeau、Maurice Shamma
      DOI：10.1016/s0040-4020(01)81486-1
      日期：1987.1
    • The photolysis of proaporphines
      作者：Belkis Gözler、Hélène Guinaudeau、Maurice Shamma、Günay Sariyar
      DOI：10.1016/s0040-4039(00)84405-6
      日期：1986.1
    查看更多

    同类化合物

    格拉齐文 呋杷文 原荷叶碱 N-乙酰基光千金藤碱 Glaziovina Suavedol Pronuciferine, (-)- Spiro(2-cyclohexene-1,7'(1'H)-cyclopent(i,j)isoquinoline)-4,6'-diol, 2',3',8',8'a-tetrahydro-5'-methoxy-1'-methyl-, (7'-alpha(S*),8'a-alpha)-(+-)- (1,1,1-Trichloro-2-methylpropan-2-yl) 10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-carboxylate (-)-orientalinone (4R)-10,11-dimethoxy-5-methylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one;hydrochloride methyl (4R)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-carboxylate Pakistanamine (4R)-10,11-dimethoxyspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one 4-[(4S)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-yl]-4-oxobutanoate (4R)-10,11-dimethoxy-5-methylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4S)-10,11-dimethoxy-5-methylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one 4-[(4R)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-yl]-4-oxobutanoate (4S)-10,11-dimethoxyspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (+)-stepharine 11,11-Dimethylspiro[3,5-dioxa-11-azoniatetracyclo[6.6.1.02,6.012,15]pentadeca-1(15),2(6),7-triene-14,4'-cyclohexa-2,5-diene]-1'-one 10,11-Dimethoxyspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (1,1,1-trichloro-2-methylpropan-2-yl) (4R)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-carboxylate 4-[(4R)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-yl]-4-oxobutanoic acid (4S)-10,11-dimethoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (1,1,1-trichloro-2-methylpropan-2-yl) (4S)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-carboxylate 4-(10,11-Dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-yl)-4-oxobutanoate 10,11-Dimethoxy-5-methylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one N-Acetyl-O-ethyl-crotonosin 4-(5',6'-dimethoxy-4-oxo-2',3',8',8a'-tetrahydro-1'H-spiro[cyclohexa-2,5-diene-1,7'-cyclopenta[ij]isoquinolin]-1'-yl)-4-oxobutanoic acid 10,11-Dimethoxy-5,5-dimethylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one 5',6'-dimethoxy-1'-[(4-methylphenyl)sulfonyl]-2',3',8',8a'-tetrahydro-1'H,4H-spiro[cyclohexa-2,5-diene-1,7'-cyclopenta[ij]isoquinolin]-4-one 1'-benzoyl-5',6'-dimethoxy-2',3',8',8a'-tetrahydro-1'H,4H-spiro[cyclohexa-2,5-diene-1,7'-cyclopenta[ij]isoquinolin]-4-one (12R)-11-methylspiro[3,5-dioxa-11-azatetracyclo[6.6.1.02,6.012,15]pentadeca-1(15),2(6),7-triene-14,4'-cyclohexa-2,5-diene]-1'-one (4R)-10,11-dimethoxy-5-(4-methylphenyl)sulfonylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4S)-10,11-dimethoxy-5-(4-methylphenyl)sulfonylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4R)-5-benzoyl-10,11-dimethoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one 4-[(4S)-10,11-dimethoxy-6'-oxospiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,3'-cyclohexa-1,4-diene]-5-yl]-4-oxobutanoic acid (4S)-5-benzoyl-10,11-dimethoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4R)-10,11-dimethoxy-5,5-dimethylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4S)-10,11-dimethoxy-5,5-dimethylspiro[5-azoniatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one (4S)-5-acetyl-10,11-dimethoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one Amuronin Crotonosine, 6-acetyl-, acetate (ester) 5-acetyl-10-ethoxy-11-methoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohexa-2,5-diene]-1'-one rac.-N-Formylstepharin 2',10,11-Trimethoxy-5-methylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohex-2-ene]-1'-one 5',10,11-Trimethoxyspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohex-2-ene]-1'-one dl-Homolinearisin 10-Methoxy-5-methylspiro[5-azatricyclo[6.3.1.04,12]dodeca-1(12),8,10-triene-2,4'-cyclohex-2-ene]-1',11-diol

    热门分子