(η5-C5H5)Ru(PPh3)H3 | 89252-27-7

• 英文名称: (η5-C5H5)Ru(PPh3)H3
• CAS: 89252-27-7
• 化学式: C₂₃H₂₃PRu
• 分子量: 431.479
• InChiKey: YFOBPSYLSHEQIA-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (η5-C5H5)Ru(PPh3)H3 、 sodium methylate 以 甲醇 为溶剂， 以78%的产率得到[(cyclopentadienyl)(ruthenium)H(PPh3)2]
  参考文献：
  名称：

  (η⁵-C₅H₅)Ru(PPh₃)H₃: a stable ruthenium (IV) trihydride

  摘要：

  Reduction of (η5-C5H5)Ru(PPh3)2Cl (2) with LiAlH4 in tetrahydrofuran leads to the trihydride (η5-C5H5)Ru(PPh3)H3(1) together with, as a minor product, the expected monohydride (η5-C5H5)Ru(PPh3)2H (3) which can be prepared efficiently by treatment of the chloride (2) with NaOMe; reduction of (η5-C5H5)Ru(Ph2PCH2CH2PPh2)Cl (4) with LiAlH4 gives only the monohydride (η5-C5H5)Ru(Ph2PCH2CH2PPh2)H (5).

  DOI：

  10.1039/c39830001278
• 作为产物：
  描述：

  lithium aluminium tetrahydride 、 二(三苯基膦)环戊二烯基氯化钌(II) 以 四氢呋喃 为溶剂， 生成 [(cyclopentadienyl)(ruthenium)H(PPh3)2] 、 (η5-C5H5)Ru(PPh3)H3
  参考文献：
  名称：

  (η⁵-C₅H₅)Ru(PPh₃)H₃: a stable ruthenium (IV) trihydride

  摘要：

  Reduction of (η5-C5H5)Ru(PPh3)2Cl (2) with LiAlH4 in tetrahydrofuran leads to the trihydride (η5-C5H5)Ru(PPh3)H3(1) together with, as a minor product, the expected monohydride (η5-C5H5)Ru(PPh3)2H (3) which can be prepared efficiently by treatment of the chloride (2) with NaOMe; reduction of (η5-C5H5)Ru(Ph2PCH2CH2PPh2)Cl (4) with LiAlH4 gives only the monohydride (η5-C5H5)Ru(Ph2PCH2CH2PPh2)H (5).

  DOI：

  10.1039/c39830001278