(7-p-tolyl-7-azabenzonorbornadiene)tetracarbonyliron | 138234-36-3

• 英文名称: (7-p-tolyl-7-azabenzonorbornadiene)tetracarbonyliron
• CAS: 138234-36-3
• 化学式: C₂₁H₁₅FeNO₄
• 分子量: 401.201
• InChiKey: QYPOMVKZPKJYCQ-ZSFFHWGOSA-N

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 9-(p-tolyl)-1,4-dihydro-1,4-epiminonaphthalene 以 四氢呋喃 为溶剂， 生成 (7-p-tolyl-7-azabenzonorbornadiene)tetracarbonyliron
  参考文献：
  名称：

  N-亲核试剂对配位羰基配体的攻击：（7-氮杂苯并降冰片二烯）四羰基铁衍生物的结构

  摘要：

  Three crystal structures of (N-substituted 7-azabenzonorbornadiene)Fe(CO)4 derivatives have been studied for substituents 7-MeSO2 (1), 7-p-CIC6H4 (2), and 7-p-MeC6H4 (3), respectively. In the solid state, an intramolecular interaction between the N-nucleophile and the nearby coordinated CO ligand is clearly seen. As the N...C = O contact distance becomes shorter, the O atom of Fe-C-O bends away from the N atom more, corresponding to a stronger interaction between the nucleophile and the coordinated CO.

  DOI：

  10.1021/om00038a074