| 210224-44-5

• CAS: 210224-44-5
• 化学式: CH₂Cl₂*C₃₂H₃₃B₁₀O₂PRuS₂
• 分子量: 838.831
• InChiKey: QVDGUQGZWPLJEW-OLTDPYIHSA-N

反应信息

• 作为产物：
  描述：

  硫代苯甲酸 、 tris(triphenylphosphine)ruthenium(II) chloride 、 bis(tetraethylammonium) decahydro-closo-decaborate 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Synthesis and molecular structure of an exo-bicyclic eleven-vertex closo-ruthenaborane [(PPh3)(C6H5COS)2RuB10H8] · (CH2Cl2)

  摘要：

  The title compound has been separated in ca 13% yield from the reaction of closo-[B10H10](2-), [(PPh3)(3)RuCl2] and C6H5COSH in CH2Cl2 solution, and characterized by elemental analysis, infrared spectroscopy, H-1 NMR and P-31 NMR spectroscopy and single-crystal X-ray diffraction analysis. The molecular structure is based on an eleven-vertex closo-type C-2V {RuB10} cluster-geometry with the ruthenium atom occupying the unique six-connected apical position. The metal center has three exopolyhedral ligands, one triphenylphosphine and two dative thiobenzoate sulfur atoms. The carbonyl oxygen atoms of two thiobenzoxy are additionally bonded to B2 and B3 atoms respectively, resulting in two exocyclic five-membered Ru-S-C-O-B rings. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00523-8