Ru3(CO)8(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2)) | 169830-01-7

• 英文名称: Ru3(CO)8(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2))
• CAS: 169830-01-7
• 化学式: C₁₇H₁₀O₈Ru₃
• 分子量: 645.472
• InChiKey: CGQWRAQARRQHAU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  2-苯基-1-丙烯 、 十二羰基三钌 以 正辛烷 为溶剂， 以8%的产率得到Ru3(CO)8(μ3-η(2):η(2):η(2)-C6H5-(η(2)-CCH3CH2))
  参考文献：
  名称：

  Synthesis and Characterization of Ru3 and Ru4 Clusters with Isopropenylbenzene and Diisopropenylbenzene Ligands

  摘要：

  The four clusters Ru-3(CO)(7)(mu(3)-eta(2):eta(2):eta(2)-C6H4-{eta(2)-CCH3CH2}(2)-1,3), 1, Ru-4(CO)(9)(mu(3)-eta(2):eta(2):eta(2)- C6H4-{eta(2)-CCH3CH2}(2)-1,3), 2, Ru-3(CO)(8)(mu(3)-eta(2):eta(2):eta(2)-C6H5-{eta(2)-CCH3CH2}), 3, and Ru-4(CO)(10)- (mu(3)-eta(2):eta(2):eta(2)-C6H5-{eta(2)-CCH3CH2}), 4, have been prepared and characterized both spectroscopically and by means of single-crystal X-ray diffraction. The presence of the propenyl substituent(s) on the aromatic ligands results in the observed preference of the rings toward a facial coordination mode, formally donating all their pi-electrons to the metal cluster unit.

  DOI：

  10.1021/om00010a060