Cp(CO)(triphenylphosphite)Mo*CBu | 213621-42-2

• 英文名称: Cp(CO)(triphenylphosphite)Mo*CBu
• CAS: 213621-42-2
• 化学式: C₂₉H₂₉MoO₄P
• 分子量: 568.461
• InChiKey: AIURKBCCOSXKFN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  tetrafluoroboric acid 、 Cp(CO)(triphenylphosphite)Mo*CBu 生成 [Cp(CO)(triphenylphosphite)Mo=CHBu]BF4
  参考文献：
  名称：

  Effect of Ligand Variation on the Site of Protonation in the Metal Carbynes CpL₂Mo⋮CBu and TpL₂Mo⋮CBu [L = CO, P(OR)₃]

  摘要：

  The site of thermodynamic protonation of the Fischer carbynes CpL2Mo=CBu and TpL(2)Mo=CBu [L = CO, P(OR)(3)] with HBF4 depends on the number of pi-acid CO ligands. As the number of carbonyls increases from zero to two and the electron density at the metal center is decreased by back-bonding, the protonation site shifts from the metal to the carbyne carbon. Parallel behavior in the Tp and Cp series of complexes allows the change in protonation site to be attributed to electronic effects in the ancillary ligands.

  DOI：

  10.1021/om990047x
• 作为产物：
  描述：

  Cl(CO)2(triphenylphosphite)2Mo*CBu 、 Cl(CO)(triphenylphosphite)3Mo*CBu 、 sodium cyclopentadienide 以 四氢呋喃 为溶剂， 生成 Cp(CO)(triphenylphosphite)Mo*CBu
  参考文献：
  名称：

  Effect of Ligand Variation on the Site of Protonation in the Metal Carbynes CpL₂Mo⋮CBu and TpL₂Mo⋮CBu [L = CO, P(OR)₃]

  摘要：

  The site of thermodynamic protonation of the Fischer carbynes CpL2Mo=CBu and TpL(2)Mo=CBu [L = CO, P(OR)(3)] with HBF4 depends on the number of pi-acid CO ligands. As the number of carbonyls increases from zero to two and the electron density at the metal center is decreased by back-bonding, the protonation site shifts from the metal to the carbyne carbon. Parallel behavior in the Tp and Cp series of complexes allows the change in protonation site to be attributed to electronic effects in the ancillary ligands.

  DOI：

  10.1021/om990047x

文献信息

• Oxidation of Metal Carbynes in the Presence of Alkynes. Alkyne Addition vs H-Shift in the Carbene Intermediate
  作者：Karen E. Torraca、Khalil A. Abboud、Lisa McElwee-White

  DOI：10.1021/om980534x

  日期：1998.9.1

  One-electron oxidation of the carbyne complex (eta(5)-C5H5)(CO)P(OPh)(3)}Mo=CCH2CH2CH2CH3 (1a) in the presence of phenylacetylene results in H-abstraction and addition of the alkyne to the resulting metal carbene. The final product of the addition is the eta(1)eta(2)-allyl complex (eta(5)-C5H5)(CO)P(OPh)(3)}Mo[eta(1):eta(2)-CHP(OPh)(3)}C(Ph)=CH(Ch(2)CH(2)CH(2)CH(3))] (2a), the structure of which was confirmed by X-ray crystallography.