fac-[Mn(1,10-phenanthroline)(CO)3(2-methyl-imidazole)]trifluoromethanesulfonate | 266337-90-0

• 英文名称: fac-[Mn(1,10-phenanthroline)(CO)3(2-methyl-imidazole)]trifluoromethanesulfonate
• CAS: 266337-90-0
• 化学式: CF₃O₃S*C₁₉H₁₄MnN₄O₃
• 分子量: 550.354
• InChiKey: GNRSKRXAQJVNFF-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2-甲基咪唑 、 [Mn(CO)3(1,10-phenanthroline)(CF3SO3)] 以 二氯甲烷 为溶剂， 生成 fac-[Mn(1,10-phenanthroline)(CO)3(2-methyl-imidazole)]trifluoromethanesulfonate
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of [Mn(phen)(CO)3(imidazole)](SO3CF3) complexes

  摘要：

  The spectroscopic and electrochemical properties of [Mn(phen)(CO)(3)(L)](+) type complexes where L is an imidazole or an imidazole derivative containing a methyl, phenyl or NO, group, have been investigated, introduction of the substituents to the cr-donor ligand has been found to produce significant changes in the electrochemical behaviour without significantly altering the fundamental electronic structure of the complexes. The oxidation potentials of the fac-[Mn(phen)(CO)(3)L](+) and mer-[Mn-(phen)(CO)(3)L](+) isomers are very different, allowing detailed electrochemical studies to be made. Cyclic voltammetry of both the fac and mer isomers provides a complete description of a cyclic process involving the following reactions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00505-8