[Mn(CO)3(1,10-phenanthroline)(CF3SO3)] | 288389-87-7

• 英文名称: [Mn(CO)3(1,10-phenanthroline)(CF3SO3)]
• 英文别名: fac-[triflate(1,10-phenanthroline)tricarbonylmanganese(I)]；fac-[Mn(1,10-phenanthroline)(CO)3trifluorosulfonato]
• CAS: 288389-87-7
• 化学式: C₁₆H₈F₃MnN₂O₆S
• 分子量: 468.249
• InChiKey: VEIVZXHPWNJJSU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  2-甲基咪唑 、 [Mn(CO)3(1,10-phenanthroline)(CF3SO3)] 以 二氯甲烷 为溶剂， 生成 fac-[Mn(1,10-phenanthroline)(CO)3(2-methyl-imidazole)]trifluoromethanesulfonate
  参考文献：
  名称：

  Spectroscopic and electrochemical properties of [Mn(phen)(CO)3(imidazole)](SO3CF3) complexes

  摘要：

  The spectroscopic and electrochemical properties of [Mn(phen)(CO)(3)(L)](+) type complexes where L is an imidazole or an imidazole derivative containing a methyl, phenyl or NO, group, have been investigated, introduction of the substituents to the cr-donor ligand has been found to produce significant changes in the electrochemical behaviour without significantly altering the fundamental electronic structure of the complexes. The oxidation potentials of the fac-[Mn(phen)(CO)(3)L](+) and mer-[Mn-(phen)(CO)(3)L](+) isomers are very different, allowing detailed electrochemical studies to be made. Cyclic voltammetry of both the fac and mer isomers provides a complete description of a cyclic process involving the following reactions.[GRAPHICS](C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00505-8
• 作为产物：
  描述：

  {MnBr(o-phenanthroline)(CO)3} 、 silver trifluoromethanesulfonate 以 not given 为溶剂， 以90%的产率得到[Mn(CO)3(1,10-phenanthroline)(CF3SO3)]
  参考文献：
  名称：

  探索负责循环电子转移诱导异构体因子的电子因子：fac- [Mn（CO）3（L'–L'）L] 0 / +配合物的合成，电化学和光谱研究

  摘要：

  摘要fac- [Mn（CO）3（L′–L′）（L）] 0 / +的光谱（IR，31P NMR和UV-Vis）和电化学研究，其中L′–L′= 1,2-采取双（二苯基膦基）乙烷（dppe）或1,10-菲咯啉（phen）和L =溴化物，三氟甲磺酸盐，咪唑（im），异烟酰胺（isn）或N-（2-羟乙基）异烟酰胺（heisn）各种配体对这些配合物的CO–Mn–L和CO–Mn–（L'–L'）键合特征的影响。报告了L = triflate / L'–L'= dppe，L = triflate / L'–L'= phen和L = is / L'–L'= phen的晶体结构，它们显示了两个Mn–O（ OSO2CF3）和Mn–N（isn）的距离相似。三羰基配合物在UV-Vis光谱的250-300和350-450 nm区域显示两个主要谱带。最低能带被指定为金属中心（MC）和金属到配体（dπ→L'–L'）电荷转移

  DOI：

  10.1016/j.ica.2005.07.012

文献信息

• Synthesis, characterization and photophysics of bimetallic manganese(I) and ruthenium(II) complexes
  作者：Murugesan Velayudham、Seenivasan Rajagopal

  DOI：10.1016/j.poly.2009.06.021

  日期：2009.9

  electrochemical properties show that there is a weak interaction between two metal centers in Mn–Ru heterobimetallic complexes. The photophysical behavior of all the complexes is studied. The Mn(I) monometallic and homobimetallic complexes have no detectable emission. In Mn–Ru heterobimetallic complexes, the attachment of Mn(I) with Ru(II) provides interesting photophysical properties.

  摘要由2,2'-联吡啶和1,10-菲咯啉配体[Mn（CO）3（NN）（4,4'-bpy）组成的一系列新型锰（I）和钌（II）单金属和双金属配合物）] +，[（CO）3（NN）Mn} 2（4,4'-bpy）] 2+和[（CO）3（NN）Mn（4,4'-bpy）Ru（NN）2Cl除已知的钌（II）络合物[Ru]外，还合成并表征了] 2+（NN = 2,2'-联吡啶，1,10-菲咯啉； 4,4'-bpy = 4,4'-联吡啶） （NN）2Cl（4,4'-bpy）] +和[Cl（NN）2Ru（4,4'-bpy）Ru（NN）2Cl] 2+。电化学性质表明，Mn-Ru异双金属配合物中的两个金属中心之间存在弱相互作用。研究了所有配合物的光物理行为。Mn（I）单金属和同双金属配合物没有可检测的发射。在Mn-Ru异双金属配合物中，Mn（I）与Ru（II）的结合提供了有趣的光物理性质。
• A Luminescent Manganese PhotoCORM for CO Delivery to Cellular Targets under the Control of Visible Light
  作者：Jorge Jimenez、Indranil Chakraborty、Annmarie Dominguez、Jorge Martinez-Gonzalez、W. M. Chamil Sameera、Pradip K. Mascharak

  DOI：10.1021/acs.inorgchem.7b02480

  日期：2018.2.19

  first luminescent manganese carbonyl-based photoCORM reported in the literature. This complex exhibits CO release under the exclusive control of low-power broadband visible light. The corresponding rhenium carbonyl complex, namely, [Re(Imdansyl)(CO)3(phen)](CF3SO3) (2), has also been reported, which is luminescent but sensitive only to UV-B (λ<315 nm) light. The entry of the manganese photoCORM into

  合成了由丹西咪唑（Imdansyl）衍生的光活性羰基锰配合物，即[Mn（Imdansyl）（CO）3（phen）]（CF 3 SO 3）（1），并对其结构进行了表征。这是文献中首次报道的基于发光锰羰基的photoCORM。该复合物在低功率宽带可见光的唯一控制下展现出CO释放。相应的羰基rh络合物，即[Re（Imdansyl）（CO）3（phen）]（CF 3 SO 3）（2），也有报道，它是发光的，但仅对UV-B（λ<315 nm）光敏感。借助于荧光显微镜已经证明了锰photoCORM进入人结肠直肠腺癌细胞（HT-29）。将装载有光CORM的癌细胞照射到可见光下会导致剂量依赖性凋亡细胞死亡。
• Photo-induced eradication of human colorectal adenocarcinoma HT-29 cells by carbon monoxide (CO) delivery from a Mn-based green luminescent photoCORM
  作者：Jorge Jimenez、Miguel N. Pinto、Jorge Martinez-Gonzalez、Pradip K. Mascharak

  DOI：10.1016/j.ica.2018.09.088

  日期：2019.1

  Exogenous CO delivery to cellular targets for salutary purposes can be readily achieved with photoactive metal carbonyl complexes (photoCORMs). Mn(I)-based photoCORMs are often favored for their ability to release CO upon triggering with visible light (suitable for phototherapy of cancer). To date, the reported Mn(I)based photoCORMs are all non-luminescent and hence the entry of these CO donors cannot be tracked within the targeted sites. A new luminescent Mn(I) photoCORM namely [Mn(CO)(3)(phen)(Pipdansyl)](CF3SO3) (3) has been reported. Synthetic strategy to isolate photoCORM(3) and its previous analogue [Mn (CO)(3)(phen)(Imdansyl)](CF3SO3) (2) has been highlighted to establish protocols for the future isolation of luminescent Mn(I)-based photoCORMs that could be employed as trackable photoCORMs for CO delivery. The entrance of 3 into human colorectal adenocarcinoma HT-29 cells has been visualized by confocal microscopic studies. Eradication of the cancer cells by CO delivery from 3 under visible light illumination has also been demonstrated.