(η-5-C5H4Et5)Mn(CO)2xe | 272437-38-4

• 英文名称: (η-5-C5H4Et5)Mn(CO)2xe
• CAS: 272437-38-4
• 化学式: C₉H₉MnO₂Xe
• 分子量: 335.397
• InChiKey: MBAINJZBDFYSBW-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (η-5-C5H4Et5)Mn(CO)2xe 、 一氧化碳 以 further solvent(s) 为溶剂， 生成 (η5-C5H4Et)Mn(CO)3
  参考文献：
  名称：

  An Investigation into the Reactivity of Organometallic Noble Gas Complexes:  A Time-Resolved Infrared Study in Supercritical Noble Gas and Alkane Solution at Room Temperature

  摘要：

  A series of Group 7 organometallic noble gas complexes, (eta(5)-C5R5)M(CO)(2)L(M = Mn and Re; R = H, Me. and Et (Mn only); L = Kr and Xe) have been characterized in supercritical noble gas solution at room temperature using fast time-resolved infrared spectroscopy. The kinetics and activation parameters for the reaction of these complexes with CO were measured and compared to the analogous alkane complexes, (eta(5)-C5H5)M(CO)(2)(n-heptane) (M = Mn and Re). Evidence obtained from values of the activation enthalpies and experiments, in which the lifetimes of (eta(5)-C5R5)Mn(CO)(2)Xe (R = H, Me, and Et) were measured as a function of [CO] at a constant [CO]/[Xe] ratio, suggests that the reaction of the noble gas complexes with CO occurs mainly via a dissociative or dissociative interchange mechanism.

  DOI：

  10.1021/jp993736v
• 作为产物：
  描述：

  (η5-C5H4Et)Mn(CO)3 、 氙气 以 further solvent(s) 为溶剂， 生成 (η-5-C5H4Et5)Mn(CO)2xe
  参考文献：
  名称：

  An Investigation into the Reactivity of Organometallic Noble Gas Complexes:  A Time-Resolved Infrared Study in Supercritical Noble Gas and Alkane Solution at Room Temperature

  摘要：

  A series of Group 7 organometallic noble gas complexes, (eta(5)-C5R5)M(CO)(2)L(M = Mn and Re; R = H, Me. and Et (Mn only); L = Kr and Xe) have been characterized in supercritical noble gas solution at room temperature using fast time-resolved infrared spectroscopy. The kinetics and activation parameters for the reaction of these complexes with CO were measured and compared to the analogous alkane complexes, (eta(5)-C5H5)M(CO)(2)(n-heptane) (M = Mn and Re). Evidence obtained from values of the activation enthalpies and experiments, in which the lifetimes of (eta(5)-C5R5)Mn(CO)(2)Xe (R = H, Me, and Et) were measured as a function of [CO] at a constant [CO]/[Xe] ratio, suggests that the reaction of the noble gas complexes with CO occurs mainly via a dissociative or dissociative interchange mechanism.

  DOI：

  10.1021/jp993736v