3,3'-dimethyl-1,1'-methylenediimidazolium tetrachlorocobaltate(II) | 850422-70-7

• 英文名称: 3,3'-dimethyl-1,1'-methylenediimidazolium tetrachlorocobaltate(II)
• CAS: 850422-70-7
• 化学式: C₉H₁₄N₄*Cl₄Co
• 分子量: 379.042
• InChiKey: DQFGFVDIDSOPIM-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 1,1'-dimethyl-3,3'-methylenediimidazolium bromide 以 四氢呋喃 、 乙醇 为溶剂， 生成 3,3'-dimethyl-1,1'-methylenediimidazolium tetrabromocobaltate(II) 、 3,3'-dimethyl-1,1'-methylenediimidazolium tetrachlorocobaltate(II)
  参考文献：
  名称：

  3,3′-Dimethyl-1,1′-methylenediimidazolium tetrachlorocobaltate(II)

  摘要：

  The title compound, (C9H14N4)[CoCl4], a methylene-bridged bis-imidazolium salt containing a tetrachlorocobaltate anion, is one of the first examples where an alkyl-bridged bisimidazolium compound could be structurally characterized. Short C - H ... Cl contacts between the imidazolium C - H bonds and the Cl atoms of the counter-anion build up a three-dimensional network and indicate that the C - H bonds are strongly polarized.

  DOI：

  10.1107/s0108270104030471