(C5(CH3)5)Ru(η3-allyl)(η2-CH3CCCH3) | 287380-04-5

• 英文名称: (C5(CH3)5)Ru(η3-allyl)(η2-CH3CCCH3)
• CAS: 287380-04-5
• 化学式: C₁₇H₂₆Ru
• 分子量: 331.463
• InChiKey: GTFZCDAHYPTWBN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  (C5(CH3)5)Ru(η3-allyl)(η2-CH3CCCH3) 以 苯 为溶剂， 生成 (C5(CH3)5)Ru(η5-(CH3CHC(CH3)CHCHCH2))
  参考文献：
  名称：

  Allyl/Alkyne Coupling Reactions Mediated by Neutral Ruthenium(II). Isolation and Characterization of Ruthenium(II) η³-Allyl η²-Alkyne Complexes

  摘要：

  In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield.

  DOI：

  10.1021/om000275n
• 作为产物：
  描述：

  2-丁炔 、 [Cp*RuCl₂(η³-allyl)] 在 Zn 作用下， 以 四氢呋喃 为溶剂， 生成 (C5(CH3)5)Ru(η3-allyl)(η2-CH3CCCH3)
  参考文献：
  名称：

  Allyl/Alkyne Coupling Reactions Mediated by Neutral Ruthenium(II). Isolation and Characterization of Ruthenium(II) η³-Allyl η²-Alkyne Complexes

  摘要：

  In contrast to the cyclization products obtained from allyl/alkyne coupling reactions in the isostructural cationic series, neutral complexes of the form (C5Me5)Ru(eta(3)-allyl)(eta(2)-alkyne) react to give acyclic eta(5)-pentadienyl complexes in high yield.

  DOI：

  10.1021/om000275n

文献信息

• Oxidatively Induced Carbonylation and Cyclization of Ruthenium(II) Vinyl−Olefin Complexes Prepared via Allyl/Alkyne Coupling
  作者：Christina M. Older、Jeffrey M. Stryker

  DOI：10.1021/om000407c

  日期：2000.8.1

  One-electron. oxidation. of otherwise unreactive ((1:4,5-eta)-1,4-pentadien-1-yl)ruthenium carbonyl complexes in acetonitrile under carbon monoxide Leads to the formation of 5-methylene-2-cyclopenten-1-ones via carbonylation, migratory cyclization, and beta-hydride elimination. Oxidation in dichloromethane produces an acyclic 1,4-pentadiene, even under a carbon monoxide atmosphere.