[Co2(μ-EtO2CC2CO2Et)(CO)6] | 97176-27-7

• 英文名称: [Co2(μ-EtO2CC2CO2Et)(CO)6]
• CAS: 97176-27-7
• 化学式: C₁₄H₁₀Co₂O₁₀
• 分子量: 456.214
• InChiKey: WZAFZBAMEFIHQE-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  Na[Mo(CO)3Cp]*2(1,2-dimethoxyethane) 、 [Co2(μ-EtO2CC2CO2Et)(CO)6] 以 四氢呋喃 为溶剂， 以57%的产率得到{CpMo(CO)2(μ-EtCO2CCCO2Et)Co(CO)3}
  参考文献：
  名称：

  Rational synthesis of tricobalt-molybdenum and -tungsten butterfly clusters with alkyne ligands

  摘要：

  The heterometallic alkyne complexes [CoM(mu-R(1)Cequivalent toCR(2))(CO)(5)Cp] (M = Mo, W; R-1 = R-2 = CO2Me, CO2Et; R-1 = H, R-2 = CO2Me) react with dicobalt octacarbonyl in refluxing toluene to give the 60-electron tetranuclear clusters [Co3M(mu(4)-(RC2R2)-C-1 2)(CO)(9)Cp] in moderate to good yields. The clusters consist of a butterfly-type metal core in which the molybdenum (or tungsten) atom occupies a wing-tip position, as shown by X-ray analysis of three of the complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01720-5
• 作为产物：
  描述：

  dicobalt octacarbonyl 、 丁炔二酸二乙酯 以 light petroleum 为溶剂， 生成 [Co2(μ-EtO2CC2CO2Et)(CO)6]
  参考文献：
  名称：

  Rational synthesis of tricobalt-molybdenum and -tungsten butterfly clusters with alkyne ligands

  摘要：

  The heterometallic alkyne complexes [CoM(mu-R(1)Cequivalent toCR(2))(CO)(5)Cp] (M = Mo, W; R-1 = R-2 = CO2Me, CO2Et; R-1 = H, R-2 = CO2Me) react with dicobalt octacarbonyl in refluxing toluene to give the 60-electron tetranuclear clusters [Co3M(mu(4)-(RC2R2)-C-1 2)(CO)(9)Cp] in moderate to good yields. The clusters consist of a butterfly-type metal core in which the molybdenum (or tungsten) atom occupies a wing-tip position, as shown by X-ray analysis of three of the complexes. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01720-5

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: Org.Verb.2, 2.2.2.5, page 87 - 101
  作者：

  DOI：——

  日期：——
• A cobalt-cobalt bond with bridging bis(dimethylgermyl)alkane and carbon monoxide
  作者：J. Barrau、N.Ben Hamida

  DOI：10.1016/s0020-1693(00)86774-2

  日期：1990.12
• Peyronel, G.; Ragni, A.; Trogu, E. F., Gazzetta Chimica Italiana, 1962, vol. 92, p. 738 - 744
  作者：Peyronel, G.、Ragni, A.、Trogu, E. F.

  DOI：——

  日期：——