[η5:η1-(C5H4CH2CH2PH-2,4,6-tri-i-propylphenyl)HfCl3(tetrahydrothiophene)] | 449143-07-1

• 英文名称: [η5:η1-(C5H4CH2CH2PH-2,4,6-tri-i-propylphenyl)HfCl3(tetrahydrothiophene)]
• 英文别名: (η5-C5H4(CH2)2PH(2,4,6-tri-i-propylphenyl))HfCl3(C4H8S)
• CAS: 449143-07-1
• 化学式: C₂₆H₄₀Cl₃HfPS
• 分子量: 700.492
• InChiKey: RLDMQRQEOSHYNG-UHFFFAOYSA-K

反应信息

• 作为反应物：
  描述：

  [η5:η1-(C5H4CH2CH2PH-2,4,6-tri-i-propylphenyl)HfCl3(tetrahydrothiophene)] 、 氯丙烯镁 以 四氢呋喃 、 乙醚 为溶剂， 以59%的产率得到[η5-C5H4(CH2)2P(2,4,6-tri-i-propylphenyl-κP)]Hf(allyl)2
  参考文献：
  名称：

  Ethylene polymerization and ethylene/styrene copolymerization with secondary phosphine-pendant and phosphide-pendant complexes of Zr and Hf

  摘要：

  Ethylene and styrene polymerizations and ethylene/styrene copolymerization have been examined with a catalytic system obtained by a combination of zirconium or hafnium complexes bearing a secondary phosphine-pendant cyclopentadienyl ligand {eta(5)-C5H4(CH2)(2)P(H)R} (R = 2,4,6-trimethylphenyl (Mes), 2,4,6-tri(i-propyl)phenyl (Tip)) or a phosphide-pendant cyclopentadienyl ligand {eta(5)-C5H4(CH2)(2)PR-kappaP} with modified methylaluminoxane (MMAO) or a mixture of methylaluminoxane (MAO) and tri-i-butylaluminium (TIBA) as a cocatalyst. These systems show moderate activity in ethylene polymerization (8-316 g mmol(-1) h(-1)) but show inactivity in styrene polymerization. In ethylene/styrene copolymerization, these systems afford ethylene/styrene copolymers with a relatively high styrene content (35-87%). (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2004.06.024