| 171975-54-5

• CAS: 171975-54-5
• 化学式: C₁₈H₁₄Ru
• 分子量: 331.379
• InChiKey: RAPDSIUUCZIMQM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-cyclopentadienyl)(η(6)-fluorene)iron(II) hexafluororophosphate 、 以 氘代二甲亚砜 为溶剂， 生成 [CpRu(η6-fluorene)](PF6) 、 dibenzoferrocene
  参考文献：
  名称：

  Deprotonation of the complexes [Ru(arene)Cp]+PF6− (arene = C6Me6 and fluorene): X-ray crystal structure of [Ru(η5-C6Me5CH2)Cp] and determination of the pKa values using the iron analogues

  摘要：

  The ruthenium complexes [RuCp(C(6)Me(6))](+) (2) and [RuCp(fluorene)](+) (6)(PF6- salts throughout this communication) have been deprotonated to 4 and 7 respectively. The X-ray crystal structure of 4 shows an angle of 34.4 (9)degrees between the cyclohexadienyl plane and the plane defined by C(11), C(12) and C(16). The pK(a) values of 2 and 6 were determined by the direct method using the analogous iron complexes and indicate promising proton-reservoir properties.

  DOI：

  10.1016/0022-328x(95)05785-n
• 作为产物：
  描述：

  [CpRu(η6-fluorene)](PF6) 在 t-BuOK 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Deprotonation of the complexes [Ru(arene)Cp]+PF6− (arene = C6Me6 and fluorene): X-ray crystal structure of [Ru(η5-C6Me5CH2)Cp] and determination of the pKa values using the iron analogues

  摘要：

  The ruthenium complexes [RuCp(C(6)Me(6))](+) (2) and [RuCp(fluorene)](+) (6)(PF6- salts throughout this communication) have been deprotonated to 4 and 7 respectively. The X-ray crystal structure of 4 shows an angle of 34.4 (9)degrees between the cyclohexadienyl plane and the plane defined by C(11), C(12) and C(16). The pK(a) values of 2 and 6 were determined by the direct method using the analogous iron complexes and indicate promising proton-reservoir properties.

  DOI：

  10.1016/0022-328x(95)05785-n