bis(acetato)bis(aquo)bis-μ-(N-(2-hydroxylethyl)-o-salicylaldiminato-N,O.O)dinikel(II) | 133454-39-4

• 英文名称: bis(acetato)bis(aquo)bis-μ-(N-(2-hydroxylethyl)-o-salicylaldiminato-N,O.O)dinikel(II)
• CAS: 133454-39-4
• 化学式: C₂₂H₃₀N₂Ni₂O₁₀
• 分子量: 599.868
• InChiKey: MKLPOHIUYQVARJ-YINHMMFWSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(acetato)bis(aquo)bis-μ-(N-(2-hydroxylethyl)-o-salicylaldiminato-N,O.O)dinikel(II) 以 甲醇 为溶剂， 以64%的产率得到[Ni(2-(((2-hydroxyethyl)imino)methyl)phenol)₂]
  参考文献：
  名称：

  Synthesis, X-ray crystal structures and linear and nonlinear optical characterization of a series of nickel(II) and copper(II) salicylaldiminato complexes

  摘要：

  A series of nickel(II) and copper(II) salicylaldiminato complexes containing side arms with either potentially coordinating (OH) or non-coordinating (0) functional groups have been prepared and characterized by X-ray crystallography. The Cu(11) complexes are square planar, but the Ni(11) complexes prefer octahedral coordination. Linear absorption spectra depend on the metal and on its coordination geometry, with the octahedral Ni(11) complexes being the most weakly absorbing at 532 nm and the square planar Cu(11) complexes being the most strongly absorbing at 532 nm. The third-order nonlinear optical properties of the complexes have been characterized using degenerate four-wave mixing (DFWM) and Z-scan. Two different Z-scan experimental configurations were used, one of which employs a Gaussian beam in a tightly focused geometry while the other employs a top-hat beam and a more relaxed focus. The observed third-order optical nonlinearity is primarily due to transient thermal (photo-acoustic) effects associated with linear absorption in the samples. The dependence of the third-order nonlinear optical properties on the linear absorption means that the nonlinear optical properties vary substantially between the complexes even though they all contain the same chromophore. The hyperpolarizability of one of the complexes, gamma = 1.3 x 10(-30) esu, rivals the nonlinearities measured at 532 nm in expanded porphyrin and phthalocyanine complexes. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.05.009
• 作为产物：
  描述：

  nickel(II) acetate tetrahydrate 、 水杨醛 、 C.I.酸性橙108 以 甲醇 为溶剂， 以91.6%的产率得到bis(acetato)bis(aquo)bis-μ-(N-(2-hydroxylethyl)-o-salicylaldiminato-N,O.O)dinikel(II)
  参考文献：
  名称：

  Synthesis, X-ray crystal structures and linear and nonlinear optical characterization of a series of nickel(II) and copper(II) salicylaldiminato complexes

  摘要：

  A series of nickel(II) and copper(II) salicylaldiminato complexes containing side arms with either potentially coordinating (OH) or non-coordinating (0) functional groups have been prepared and characterized by X-ray crystallography. The Cu(11) complexes are square planar, but the Ni(11) complexes prefer octahedral coordination. Linear absorption spectra depend on the metal and on its coordination geometry, with the octahedral Ni(11) complexes being the most weakly absorbing at 532 nm and the square planar Cu(11) complexes being the most strongly absorbing at 532 nm. The third-order nonlinear optical properties of the complexes have been characterized using degenerate four-wave mixing (DFWM) and Z-scan. Two different Z-scan experimental configurations were used, one of which employs a Gaussian beam in a tightly focused geometry while the other employs a top-hat beam and a more relaxed focus. The observed third-order optical nonlinearity is primarily due to transient thermal (photo-acoustic) effects associated with linear absorption in the samples. The dependence of the third-order nonlinear optical properties on the linear absorption means that the nonlinear optical properties vary substantially between the complexes even though they all contain the same chromophore. The hyperpolarizability of one of the complexes, gamma = 1.3 x 10(-30) esu, rivals the nonlinearities measured at 532 nm in expanded porphyrin and phthalocyanine complexes. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.05.009

文献信息

• Synthesis, Crystal Structure and Properties of a Di‐μ‐phenoxo Dinuclear Nickel(II) Complex with a Tridentate Schiff Base Ligand
  作者：Huiyan Liu、Haiying Wang、Dezhong Niu、Zaisheng Lu、Jing Sun

  DOI：10.1081/sim-200052660

  日期：2005.4.1

  A new di‐μ‐phenoxo dinuclear nickel(II) complex, [Ni2(Hsae)2(CH3COO)2(H2O)2] (H2sae = salicylidene‐2‐ethanolamine), has been synthesized and characterized by molar conductances, electronic spectra, IR spectra and cyclic voltammetry. The X‐ray structure analysis of this novel nickel(II) complex (C22H30N2O10Ni2, monoclinic, P2(1)/n, a = 9.554(20) Å, b = 17.65(4) Å, c = 15.10(3) Å, β = 95.04(4)°, Z = 4)

  合成了一种新的二-μ-苯氧基双核镍 (II) 配合物 [Ni2(Hsae)2(CH3COO)2(H2O)2] (H2sae = 水杨基-2-乙醇胺)，并通过摩尔电导、电子光谱进行了表征，红外光谱和循环伏安法。这种新型镍 (II) 配合物 (C22H30N2O10Ni2, 单斜晶, P2(1)/n, a = 9.554(20) Å, b = 17.65(4) Å, c = 15.10(3) Å, β = 95.04(4)°, Z = 4) 表明该配合物由一个双核单元组成，两个镍 (II) 离子通过苯氧基双桥接。每个镍(II)离子都采用扭曲的八面体结构，其中来自席夫碱配体的NO3供体组形成赤道面，其余轴向位置被乙酸盐和水的O2供体组占据。徐州师范大学自然科学基金（No.