[iron(III)Cl(5-(4-carboxyphenyl)-10,15,20-tritolylporphyrin)] | 863764-12-9

• 英文名称: [iron(III)Cl(5-(4-carboxyphenyl)-10,15,20-tritolylporphyrin)]
• CAS: 863764-12-9
• 化学式: C₄₈H₃₄ClFeN₄O₂
• 分子量: 790.124
• InChiKey: YOMYXXQLCXTGNO-UGEMGFOCSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  三氯化铁 、 5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin 以 N,N-二甲基甲酰胺 为溶剂， 生成 [iron(III)Cl(5-(4-carboxyphenyl)-10,15,20-tritolylporphyrin)]
  参考文献：
  名称：

  The electronic and magnetic properties of iron(III) derivatives of selected substituted meso-tetraphenyl porphyrins: ESR spectroscopic study

  摘要：

  The electronic and magnetic behaviour of the nonsolvated ferric complexes of: (a) meso-tetratolyl-, (b) meso-tetra-4-hydroxyphenyl-, (c) meso-tetra-4-carboxyphenyl-, and (d) 5-(4-carboxyphenyl)-10,15,20-tritolyl-porphyrins was studied by ESR spectroscopy in the temperature range between 300 and 4 K. The complexes exhibit predominant contribution from the low-spin iron species at high temperature and a drastic shift toward the high-spin iron species at the low-temperature limit. These paramagnetic species are in different proportions at different temperatures, as well as in porphyrins with different substituents. The examined porphyrins obtained as disordered solids contain iron complexes with continuous short-range disorder which is additionally sensitive to change of temperature. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.jpcs.2004.07.008