[5α,10β,15α,20β-tetrakis(2-chloro-6-hydroxyphenyl)porphinato-N(21),N(22),N(23),N(24)]manganese chloride | 219304-54-8

• 英文名称: [5α,10β,15α,20β-tetrakis(2-chloro-6-hydroxyphenyl)porphinato-N(21),N(22),N(23),N(24)]manganese chloride
• CAS: 219304-54-8
• 化学式: C₄₄H₂₄Cl₅MnN₄O₄
• 分子量: 904.902
• InChiKey: ZLGBOAZTHDPJSB-UORDIIKZSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [5α,10β,15α,20β-tetrakis(2-chloro-6-hydroxyphenyl)porphinato-N(21),N(22),N(23),N(24)]manganese chloride 、 4-Brommethyl-<2.2>paracyclophan 在 potassium carbonate 作用下， 以 二氯甲烷 为溶剂， 以100%的产率得到[5α,10β,15α,20β-tetrakis(2-chloro-6-(5-((S)-tricyclo[8.2.2.2(4,7)] hexadeca-4,6,10,12,13,15-hexaene)methoxy)phenyl)porphinato-N(21),N(22),N(23),N(24)]manganese chloride
  参考文献：
  名称：

  [2.2]-para-Cyclophane-4-carbaldehyde as building-block for chiral ligands

  摘要：

  The synthesis of the Mn(III)-complex of the new enantiopure, atropoisomerically pure chiral porphyrin (alpha,beta,alpha,beta)-1 is described. The compound was used as the catalyst in the epoxidation of unfunctionalized olefins using aqueous NaOCl, 30%-H2O2 or PhIO as oxygen donors. Up to 780 overall turnovers were obtained in the presence of NaOCl and PhIO, whereas with 30%-H2O2 only catalase activity was observed. Contrary to expectations based on previous results [S. Banfi, A. Manfredi, F. Montanari, G. Pozzi, S. Quici, J. Mel. Catal., 113 (1996) 77], only racemic epoxides were obtained. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(98)00011-9
• 作为产物：
  描述：

  5α,10β,15α,20β-tetrakis(2-chloro-6-hydroxyphenyl)porphyrin 、 manganese (II) acetate tetrahydrate 以 N,N-二甲基甲酰胺 为溶剂， 以66%的产率得到[5α,10β,15α,20β-tetrakis(2-chloro-6-hydroxyphenyl)porphinato-N(21),N(22),N(23),N(24)]manganese chloride
  参考文献：
  名称：

  [2.2]-para-Cyclophane-4-carbaldehyde as building-block for chiral ligands

  摘要：

  The synthesis of the Mn(III)-complex of the new enantiopure, atropoisomerically pure chiral porphyrin (alpha,beta,alpha,beta)-1 is described. The compound was used as the catalyst in the epoxidation of unfunctionalized olefins using aqueous NaOCl, 30%-H2O2 or PhIO as oxygen donors. Up to 780 overall turnovers were obtained in the presence of NaOCl and PhIO, whereas with 30%-H2O2 only catalase activity was observed. Contrary to expectations based on previous results [S. Banfi, A. Manfredi, F. Montanari, G. Pozzi, S. Quici, J. Mel. Catal., 113 (1996) 77], only racemic epoxides were obtained. (C) 1998 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(98)00011-9