| 202287-47-6

• CAS: 202287-47-6
• 化学式: C₃₅H₃₈OP₂W
• 分子量: 720.484
• InChiKey: JDOFXAFTHQZOMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  W(PhC.tplbond.CPh)3(PMe3) 、 、 二甲基苯基磷 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Mechanistic information of substitution reaction of W(PhC≡CPh)3(CO) with trimethylphosphine

  摘要：

  Substitution reaction of W(PhC=CPh)(3)(CO) (1) with PMe3 to give W(PhC=CPh)(3)(PMe3) (2) has been studied by IR and NMR spectroscopy as well as cross-over experiments. A metastable intermediate W(CO)(PhC=CPh)(2)(PMe3)(2) (3) is produced by adding two PMe, moieties into 1 accompanied with loss of a PhC=CPh ligand. Subsequent conversion from 3 to 2 might involve decarbonylation and PMe3/PhC=CPh exchange. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00418-x
• 作为产物：
  描述：

  tris(diphenylacetylene)tungsten monocarbonyl 、 三甲基膦 以 二氯甲烷 为溶剂， 以74%的产率得到W(PhC.tplbond.CPh)3(PMe3)
  参考文献：
  名称：

  Mechanistic information of substitution reaction of W(PhC≡CPh)3(CO) with trimethylphosphine

  摘要：

  Substitution reaction of W(PhC=CPh)(3)(CO) (1) with PMe3 to give W(PhC=CPh)(3)(PMe3) (2) has been studied by IR and NMR spectroscopy as well as cross-over experiments. A metastable intermediate W(CO)(PhC=CPh)(2)(PMe3)(2) (3) is produced by adding two PMe, moieties into 1 accompanied with loss of a PhC=CPh ligand. Subsequent conversion from 3 to 2 might involve decarbonylation and PMe3/PhC=CPh exchange. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00418-x