4,4'-bromo-[2,2'-[ethane-1,2-diil-bis(nitrilo-methylidyne)]diphenolato]-manganese(III)-chloride | 941672-30-6

• 英文名称: 4,4'-bromo-[2,2'-[ethane-1,2-diil-bis(nitrilo-methylidyne)]diphenolato]-manganese(III)-chloride
• CAS: 941672-30-6
• 化学式: C₁₆H₁₂Br₂ClMnN₂O₂
• 分子量: 514.482
• InChiKey: YMWVSURATHZJJU-OCMVVAPRSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  manganese (II) acetate tetrahydrate 、 乙二胺 、 5-溴水杨醛 、 lithium chloride 以 乙醇 为溶剂， 生成 4,4'-bromo-[2,2'-[ethane-1,2-diil-bis(nitrilo-methylidyne)]diphenolato]-manganese(III)-chloride
  参考文献：
  名称：

  Effect of substituents on the Mn(III)Salen catalyzed oxidation of styrene

  摘要：

  dManganese(III)complexes of Salen, Br(2)Salen and (tert-butyl)(4)Salen ligands and their encapsulated analogues were prepared by the intrazeolite ligand synthesis (template synthesis) method. The oxidation of styrene was studied on the above catalysts using molecular oxygen as oxidant and tert-butyl hydroperoxide as initiator. The progress of the reactions was followed both by gas chromatography and by the oxygen consumed. The effect of the substituents on the encapsulation, on the catalytic activity and the effect of the encapsulation on the catalytic activity were studied and discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(01)00112-1