[Cu(trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine)]2 | 1072923-48-8

• 英文名称: [Cu(trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine)]2
• CAS: 1072923-48-8
• 化学式: C₄₀H₄₀Cu₂N₄O₄
• 分子量: 767.874
• InChiKey: INWYQVLSMZRJQI-LTHARETESA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Cu(trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine)]2 以 neat (no solvent) 为溶剂， 生成 copper(II) oxide
  参考文献：
  名称：

  Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N′-bis(salicylidene)-1′,2′-cyclohexanediamine with Cu(II)

  摘要：

  The dimeric complex, [C20H2OCuN2O2](2). has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H center dot center dot center dot O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltarnmetry at 100 mV s(-1) scan rate. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.12.015
• 作为产物：
  描述：

  rac-trans-N,N'-bis(salicylidene)-1,2-cyclohexanediamine 、 copper(II) acetate monohydrate 以 乙腈 为溶剂， 以75%的产率得到[Cu(trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine)]2
  参考文献：
  名称：

  Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N′-bis(salicylidene)-1′,2′-cyclohexanediamine with Cu(II)

  摘要：

  The dimeric complex, [C20H2OCuN2O2](2). has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H center dot center dot center dot O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltarnmetry at 100 mV s(-1) scan rate. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.12.015