| 191165-99-8

• CAS: 191165-99-8
• 化学式: C₁₄H₁₀Br₄N₂Ru*C₃₅H₂₅BrN₅Ru
• 分子量: 1323.52
• InChiKey: NTUOVVCOKVAFPZ-UHFFFAOYSA-I

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 苯甲醇 以 苯甲醇 为溶剂， 生成
  参考文献：
  名称：

  Ruthenium-mediated dehydration of benzaldehyde oxime. X-ray crystal structure of the mixed-valence compound [RuBr(NCPh)5][RuBr4(NCPh)2]·PhCH2OH

  摘要：

  The reaction between RuBr3 . xH(2)O and benzaldehyde oxime in aqueous 6 M HBr results in facile metal-assisted dehydration of the oxime and concomitant partial reduction of ruthenium(III) to produce the mixed-valence ruthenium(III)-ruthenium(II) compound [RuBr(N=CPh)(5)][RuBr4(N=CPh)(2)]. This ionic complex has been structurally characterized as the monobenzyl alcohol solvate, [RuBr(N=CPh)(5)][RuBr4(N=CPh)2]. PhCH2OH. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00574-8
• 作为产物：
  描述：

  ruthenium(III) bromide hydrate 、 苯甲醛肟 以 氢溴酸 为溶剂， 以23%的产率得到
  参考文献：
  名称：

  Ruthenium-mediated dehydration of benzaldehyde oxime. X-ray crystal structure of the mixed-valence compound [RuBr(NCPh)5][RuBr4(NCPh)2]·PhCH2OH

  摘要：

  The reaction between RuBr3 . xH(2)O and benzaldehyde oxime in aqueous 6 M HBr results in facile metal-assisted dehydration of the oxime and concomitant partial reduction of ruthenium(III) to produce the mixed-valence ruthenium(III)-ruthenium(II) compound [RuBr(N=CPh)(5)][RuBr4(N=CPh)(2)]. This ionic complex has been structurally characterized as the monobenzyl alcohol solvate, [RuBr(N=CPh)(5)][RuBr4(N=CPh)2]. PhCH2OH. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(96)00574-8