[Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]BF4 | 318294-07-4

• 英文名称: [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]BF4
• CAS: 318294-07-4
• 化学式: BF₄*C₁₈H₂₂ClO₂Ru₂
• 分子量: 594.769
• InChiKey: XVBHMZSMOPZHFH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]BF4 以 not given 为溶剂， 生成 [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]PF6
  参考文献：
  名称：

  Synthesis and Photochromic Property ofcis-Azobenzene Complex with a Binuclear η⁶-Areneruthenium(II) Unit

  摘要：

  顺式偶氮苯络合物由相应的双核乙腈络合物（3）和经紫外线（300 nm < λ < 400 nm）照射的反式偶氮苯合成，其中反式偶氮苯由连接到η6-芳烃供体（4）的烷氧基配体桥联。在乙腈中用可见光（λ > 510 nm）照射时，4大部分解离为反式偶氮苯，3的光稳态比为3/4 = 92/8。

  DOI：

  10.1246/cl.2000.1334
• 作为产物：
  描述：

  氟硼酸钠 、 [Ru(η6-C6H5(CH2)3OH)Cl2]2 、 C.I.酸性橙108 以 乙腈 为溶剂， 以80%的产率得到[Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]BF4
  参考文献：
  名称：

  Synthesis and Photochromic Property ofcis-Azobenzene Complex with a Binuclear η⁶-Areneruthenium(II) Unit

  摘要：

  顺式偶氮苯络合物由相应的双核乙腈络合物（3）和经紫外线（300 nm < λ < 400 nm）照射的反式偶氮苯合成，其中反式偶氮苯由连接到η6-芳烃供体（4）的烷氧基配体桥联。在乙腈中用可见光（λ > 510 nm）照射时，4大部分解离为反式偶氮苯，3的光稳态比为3/4 = 92/8。

  DOI：

  10.1246/cl.2000.1334

文献信息

• Conversion of Allylic Alcohols to Carbonyl Compounds Catalyzed by Alkoxy-Bridged Dinuclear Areneruthenium Complexes
  作者：Yasutomo Takai、Ryo Kitaura、Emi Nakatani、Takafumi Onishi、Hideo Kurosawa

  DOI：10.1021/om050442p

  日期：2005.9.1

  the methoxy-bridged complex [Ru2η6:η1:μ-C6H5(CH2)3O}2(μ-OMe)]BF4 with HOTf also resulted in generation of catalyst for the isomerization, while these dinuclear complexes themselves were inactive as the isomerization catalyst. Reaction of the hydride-bridged dinuclear complex [Ru2η6:η1:μ-C6H5(CH2)3O}2(μ-H)]BF4 with methyl vinyl ketone gave the allyloxy-bridged dinuclear complex [Ru2η6:η1:μ-C6H5(C

  的可见光照射偶氮苯桥连的双核钌络合物由η结扎6具有侧烷氧基配体，[茹-arene组2 η 6：η 1：μ-C 6 H ^ 5（CH 2）3 Ô} 2（ μ- C6 H 5 N NC 6 H 4 OMe）] BF 4导致了能够在温和条件下催化烯丙醇异构化为相应羰基化合物的活性物种。的氯桥双核配合物的治疗的[Ru 2 η 6：η 1：μ-C 6 H ^ 5（CH 2）3 Ô} 2（μ-Cl）的] BF 4与1当量的AgOTf或所述的甲氧基-桥连的络合物的[Ru 2 η 6：η 1：μ-C 6 ħ具有HOTf的5（CH 2）3 O} 2（μ-OMe）] BF 4也导致产生用于异构化的催化剂，而这些双核络合物本身作为异构化催化剂是不活泼的。所述的反应氢化-桥连的双核配合物的[Ru 2 η 6：η 1：μ-C 6 ħ5（CH 2）3 Ô} 2（μ-H）] BF 4用甲基乙烯基酮，得到烯丙氧基-桥连的双核配合物的[Ru
• Bridge coordination of bidentate ligands to a dinuclear η6-arene-ruthenium(II) unit constructed by a chelating and bridging alkoxo ligand
  作者：Ryo Kitaura、Yoshiharu Miyaki、Takafumi Onishi、Hideo Kurosawa

  DOI：10.1016/s0020-1693(02)00751-x

  日期：2002.5

  Dinuclear eta(6)-areneruthenium(II) complex of the formula [Ru-2eta(6):eta(1):mu-C6H5(CH2)(3)O} (mu-Cl)](+) (2) was prepared by treatment of Rumu(6)-C6H5(CH2)(3)OH}Cl-2 with base. X-Ray structure analysis revealed 2 to contain two Ru centers bridged by Cl ligand as well as by two alkoxo groups, which are tethered to eta(6)-arene ligands. Treatment of 2 with Ag+ in acetonitrile afforded dicationic complex [Ru-2eta(6):eta(1):mu-C6H5(CH)(3)O}(2)(CH3CN)(2)](2+) (3) in which two CH3CN ligands are located trans to each other with respect to the Ru2O2 plane. Irradiation with UV light (300-400 nm) of a CH3CN solution of 3 and trams-azobenzene gave cis-azobenzene complex [Ru-2eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-cis-PhN=NPh)](2+) (4). Cis-azobenzene ligand of 4 dissociated under irradiation of light (> 510 nm) to give 3 in CH3CN or disulfide complex [Ru-2eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-PhSSPh)](2+) (6) in the presence of the disulfide. X-ray structure determination of 4 and 6 established bridge coordination of cis-azobenzene and disulfide ligands. Reaction of 3 with pyridazine afforded similar dimeric complex [Ru-2eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-pyridazine)](2+) (7), while the reaction with bipyridine afforded monomeric alkoxo chelate complex [Rueta(6):eta(1)-C6H5(CH2)(3)O}(bipy)](+) (8). (C) 2002 Elsevier Science B.V. All rights reserved.