[Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]PF6 | 318294-12-1

• 英文名称: [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]PF6
• CAS: 318294-12-1
• 化学式: C₁₈H₂₂ClO₂Ru₂*F₆P
• 分子量: 652.929
• InChiKey: PPFKGIFJNQZFTB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  六氟磷酸银 、 [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]PF6 、 乙腈 以 乙腈 为溶剂， 生成 [Ru2(η6:η1:μ-C6H5(CH2)3O)2(CH3CN)2](PF6)2
  参考文献：
  名称：

  Bridge coordination of bidentate ligands to a dinuclear η6-arene-ruthenium(II) unit constructed by a chelating and bridging alkoxo ligand

  摘要：

  Dinuclear eta(6)-areneruthenium(II) complex of the formula [Ru-2{eta(6):eta(1):mu-C6H5(CH2)(3)O} (mu-Cl)](+) (2) was prepared by treatment of Ru{mu(6)-C6H5(CH2)(3)OH}Cl-2 with base. X-Ray structure analysis revealed 2 to contain two Ru centers bridged by Cl ligand as well as by two alkoxo groups, which are tethered to eta(6)-arene ligands. Treatment of 2 with Ag+ in acetonitrile afforded dicationic complex [Ru-2{eta(6):eta(1):mu-C6H5(CH)(3)O}(2)(CH3CN)(2)](2+) (3) in which two CH3CN ligands are located trans to each other with respect to the Ru2O2 plane. Irradiation with UV light (300-400 nm) of a CH3CN solution of 3 and trams-azobenzene gave cis-azobenzene complex [Ru-2{eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-cis-PhN=NPh)](2+) (4). Cis-azobenzene ligand of 4 dissociated under irradiation of light (> 510 nm) to give 3 in CH3CN or disulfide complex [Ru-2{eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-PhSSPh)](2+) (6) in the presence of the disulfide. X-ray structure determination of 4 and 6 established bridge coordination of cis-azobenzene and disulfide ligands. Reaction of 3 with pyridazine afforded similar dimeric complex [Ru-2{eta(6):eta(1):mu-C6H5(CH2)(3)O}(2)(mu-pyridazine)](2+) (7), while the reaction with bipyridine afforded monomeric alkoxo chelate complex [Ru{eta(6):eta(1)-C6H5(CH2)(3)O}(bipy)](+) (8). (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)00751-x
• 作为产物：
  描述：

  [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]BF4 以 not given 为溶剂， 生成 [Ru2(η6:η1:μ-C6H5(CH2)3O)2(μ-Cl)]PF6
  参考文献：
  名称：

  Synthesis and Photochromic Property ofcis-Azobenzene Complex with a Binuclear η⁶-Areneruthenium(II) Unit

  摘要：

  顺式偶氮苯络合物由相应的双核乙腈络合物（3）和经紫外线（300 nm < λ < 400 nm）照射的反式偶氮苯合成，其中反式偶氮苯由连接到η6-芳烃供体（4）的烷氧基配体桥联。在乙腈中用可见光（λ > 510 nm）照射时，4大部分解离为反式偶氮苯，3的光稳态比为3/4 = 92/8。

  DOI：

  10.1246/cl.2000.1334