[(C5H5)Fe(C5H4CCPH(2,4,6-(tert-butyl)3C6H2))] | 855791-13-8

• 英文名称: [(C5H5)Fe(C5H4CCPH(2,4,6-(tert-butyl)3C6H2))]
• CAS: 855791-13-8
• 化学式: C₃₀H₃₉FeP
• 分子量: 486.46
• InChiKey: NLEQQMLELQAQEN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 [(C5H5)Fe(C5H4CCPH(2,4,6-(tert-butyl)3C6H2))] 在 正丁基锂 、 1,2-二溴乙烷 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 以64%的产率得到1,2-diferrocenyl-3,4-diphosphinidenecyclobutene methylenedichloride monosolvate
  参考文献：
  名称：

  Preparation and Properties of 1,2-Diferrocenyl-Substituted 3,4-Diphosphinidenecyclobutenes and Their Complexes:  The First Application of a Diphosphinidenecyclobutene Unit as a Linker of Functional Moieties

  摘要：

  Compounds with two ferrocenyl units connected with 3,4-diphosphinidenecyclobutene (DPCB) linkers at the 1,2-positions (1) and their transition metal chelate complexes (2) were prepared, and the spectroscopic and electrochemical properties were studied. The compounds were examined by cyclic voltammetry, and Delta E(1/2) values (the separation between successive Fe(2+)/Fe(3+) oxidation potentials) were determined. Being fully conjugated with DPCB linkers, those compounds demonstrated electrochemical communication: the Cr(CO)(4) complex of 1 (2Cr) showed a strong interaction (Delta E(1/2) = 350 mV), whereas PdCl(2) and PtCl(2) complexes of 1 (2Pd and 2Pt) displayed a decreased interaction compared to that of 1.

  DOI：

  10.1021/om0500772
• 作为产物：
  描述：

  1,1-dibromo-2-ferrocenylethene 、 (2,4,6-tri-tert-butyl)phenylmonochlorophosphane 以 四氢呋喃 、 正己烷 为溶剂， 以60%的产率得到[(C5H5)Fe(C5H4CCPH(2,4,6-(tert-butyl)3C6H2))]
  参考文献：
  名称：

  Preparation and Properties of 1,2-Diferrocenyl-Substituted 3,4-Diphosphinidenecyclobutenes and Their Complexes:  The First Application of a Diphosphinidenecyclobutene Unit as a Linker of Functional Moieties

  摘要：

  Compounds with two ferrocenyl units connected with 3,4-diphosphinidenecyclobutene (DPCB) linkers at the 1,2-positions (1) and their transition metal chelate complexes (2) were prepared, and the spectroscopic and electrochemical properties were studied. The compounds were examined by cyclic voltammetry, and Delta E(1/2) values (the separation between successive Fe(2+)/Fe(3+) oxidation potentials) were determined. Being fully conjugated with DPCB linkers, those compounds demonstrated electrochemical communication: the Cr(CO)(4) complex of 1 (2Cr) showed a strong interaction (Delta E(1/2) = 350 mV), whereas PdCl(2) and PtCl(2) complexes of 1 (2Pd and 2Pt) displayed a decreased interaction compared to that of 1.

  DOI：

  10.1021/om0500772