[(η5-C5Me5)Fe(μ-S-2-(trimethylsilyl)phenyl)]2 | 1370318-37-8

• 英文名称: [(η5-C5Me5)Fe(μ-S-2-(trimethylsilyl)phenyl)]2
• CAS: 1370318-37-8
• 化学式: C₃₈H₅₆Fe₂S₂Si₂
• 分子量: 744.86
• InChiKey: BXKLOKTXLVRDHJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 [(η5-C5Me5)Fe(μ-S-2-(trimethylsilyl)phenyl)]2 以 四氢呋喃 为溶剂， 生成 [((η5-C5Me5)Fe)2(μ-S-2-(trimethylsilyl)phenyl)(μ-η2:η2-NHNMe)][OTf]
  参考文献：
  名称：

  Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines

  摘要：

  Novel thiolate-bridged diiron complexes bearing diazenido and diazene ligands in a side-on manner have been prepared and characterized by X-ray analysis. These sulfur-bridged diiron complexes work as effective catalysts toward the reduction of hydrazines into amines and ammonia via a sequential process of protonation and reduction on the sulfur-bridged diiron skeleton, as is likely observed at the active site of nitrogenase.

  DOI：

  10.1021/om300134t
• 作为产物：
  描述：

  [FeClCp*(TMEDA)] 、 K(S-2-(trimethylsilyl)phenyl) 以 四氢呋喃 为溶剂， 以77%的产率得到[(η5-C5Me5)Fe(μ-S-2-(trimethylsilyl)phenyl)]2
  参考文献：
  名称：

  Synthesis of Sulfur- and Nitrogen-Bridged Diiron Complexes and Catalytic Behavior toward Hydrazines

  摘要：

  Novel thiolate-bridged diiron complexes bearing diazenido and diazene ligands in a side-on manner have been prepared and characterized by X-ray analysis. These sulfur-bridged diiron complexes work as effective catalysts toward the reduction of hydrazines into amines and ammonia via a sequential process of protonation and reduction on the sulfur-bridged diiron skeleton, as is likely observed at the active site of nitrogenase.

  DOI：

  10.1021/om300134t