Ru(C5Me5)(η(4)-2-(tert-butyldimethylsiloxy)-4-methyl-1,3-pentadiene)Cl | 258356-11-5

• 英文名称: Ru(C5Me5)(η(4)-2-(tert-butyldimethylsiloxy)-4-methyl-1,3-pentadiene)Cl
• CAS: 258356-11-5
• 化学式: C₂₂H₃₉ClORuSi
• 分子量: 484.16
• InChiKey: STTGTEPHCWUPQU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ru(C5Me5)(η(4)-2-(tert-butyldimethylsiloxy)-4-methyl-1,3-pentadiene)Cl 以 neat (no solvent) 为溶剂， 生成 Ru(C5Me5)(η(5)-2-(tert-butyldimethylsiloxy)-4-methylpentadienyl)
  参考文献：
  名称：

  Synthesis and characterization of siloxy-substituted diene and dienyl complexes of the Ru(C5Me5) fragment

  摘要：

  The reaction of a 2-siloxy-4-methyl-1,3-pentadiene with the Ru(C5Me5)Cl tetramer was observed to lead first to an isolable Ru(C5Me5)(eta(4)-diene)Cl complex, which subsequently was found to lose HCl readily, leading to the expected Ru(C5Me5)(eta(5)-2-siloxy-4-methylpentadienyl) complex. Both species have been characterized spectroscopically and through X-ray diffraction studies. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00355-2
• 作为产物：
  描述：

  pentamethylcyclopentadienylruthenium chloride tetramer 、 tert-butyl (dimethyl)[(4-methylpenta-1,3-dien-2-yl)oxy]silane 以 四氢呋喃 为溶剂， 以41%的产率得到Ru(C5Me5)(η(4)-2-(tert-butyldimethylsiloxy)-4-methyl-1,3-pentadiene)Cl
  参考文献：
  名称：

  Synthesis and characterization of siloxy-substituted diene and dienyl complexes of the Ru(C5Me5) fragment

  摘要：

  The reaction of a 2-siloxy-4-methyl-1,3-pentadiene with the Ru(C5Me5)Cl tetramer was observed to lead first to an isolable Ru(C5Me5)(eta(4)-diene)Cl complex, which subsequently was found to lose HCl readily, leading to the expected Ru(C5Me5)(eta(5)-2-siloxy-4-methylpentadienyl) complex. Both species have been characterized spectroscopically and through X-ray diffraction studies. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00355-2