(p-cymene)Ru(Se2C2B10H10) | 874783-41-2

• 英文名称: (p-cymene)Ru(Se2C2B10H10)
• CAS: 874783-41-2
• 化学式: C₁₂H₂₄B₁₀RuSe₂
• 分子量: 535.423
• InChiKey: MANKBCZRKSRQFX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (p-cymene)Ru(Se2C2B10H10) 、 3-丁炔-2-酮 在 正丁基锂 作用下， 以 二氯甲烷 为溶剂， 以60 mg的产率得到
  参考文献：
  名称：

  Synthesis and Structural Characterization of the Ruthenium Complexes Based on ortho-Carborane-1,2-diselenolate Ligand and Terminal Alkynone

  摘要：

  lithium, selenium, and [(p-cymene)RuCl2]2 under argon leads to 16-electron complex (p-cymene)Ru(Se2C2B10H10) (1), and [(p-cymene)RuCl2]2 reacts with Li2(Se2C2B10H10) in the presence of excess sulfur to generate dinuclear complex (p-cymene)Ru(µ-S2)Ru(Se2C2B10H10)2 (2). Treatment of 1 and 2 with HC≡CCOCH3 affords addition complexes (p-cymene)Ru(Se2C2B10H10)(HC=C−COCH3) (3) and (p-cymene)Ru(µ-S2)Ru(Se2C2B10H10)2(R1C=CR2)

  DOI：

  10.1134/s0036023622600654
• 作为产物：
  描述：

  [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂ 、 dilithium 1,2-dicarba-closo-dodecaborane(12)-1,2-diselenolate 以 四氢呋喃 、 乙醚 为溶剂， 反应 2.0h， 生成 (p-cymene)Ru(Se2C2B10H10)
  参考文献：
  名称：

  Construction of 18-electron arene-ruthenium complexes based on ortho-carborane-1,2-diselenolate ligand

  摘要：

  Treatment of ortho-carborane, n-butyl lithium, selenium and [(p-cymene) RuCl2](2) under argon leads to complexes (p-cymene) Ru(Se2C2B10H10) (I) and (p-cymene)(2)Ru-2(mu(2)-Se2C2B10H10) (II). The further reaction of 16-electron complex I with RC CCO2Me affords addition complexes (p-cymene)Ru(Se2C2B10H10)(RC= C-CO2Me) (III) (R = H (IIIa); CO2Me (IIIb)). These complexes were characterized by elemental analysis, mass, and NMR spectroscopy. X-ray structural analyses were performed on II and IIIa.

  DOI：

  10.1134/s1070328414060013

文献信息

• Synthesis of heteronuclear (MoRu2) clusters from 16-electron half-sandwich complexes (p-Cymene)Ru[E2C2(B10H10)] (E=S, Se)
  作者：Shuang Liu、Xin Wang、Guo-Xin Jin

  DOI：10.1016/j.jorganchem.2005.09.034

  日期：2006.1

  The heterometallic cluster complexes (p-Cymene)Ru[S2C2(B10H10)]}Mo(CO)(2)(CO)(3)Ru[S2C2(B10H10)]} (2) and (p-Cymene)Ru[Se2C2(B10H10)]}(2)Mo(CO)(2) (3) (p-Cymene = eta(6)-4-isopropyl-toluene) have been synthesized from the reactions of 16-electron half-sandwich ruthenium 1,2-dichalcogenolate carborane complexes (p-Cymene)Ru[E2C2(B10H10)] (E = S(1a), Se(1b)) with Mo(CO)(3)(Py)(3) in the presence of BF3 (.) Et2O. The complexes of 2 and 3 were characterized by elemental analysis and IR, NMR spectra. The molecular structure of 2 has been characterized by single-crystal X-ray diffraction analysis. Complex 2 is unsymmetrical and the two Ru-Mo single bonds (2.7893(14). 2.8189(13) angstrom) are each supported by a symmetrically bridging o-carborane-1,2-dithiolato ligand. (c) 2005 Elsevier B.V. All rights reserved.
• Multinuclear Self-Assembly via a (<i>p</i>-Cymene)ruthenium Unit and an <i>o</i>-Carborane Selenolate Ligand
  作者：Jiurong Hu、Jialin Wen、Dehong Wu、Rui Zhang、Guifeng Liu、Qibai Jiang、Yizhi Li、Hong Yan

  DOI：10.1021/om1010275

  日期：2011.1.24

  Treatment of o-carborane, n-butyllithium, selenium, and [(p-cymene)RuCl2](2) under argon leads to the complexes (p-cymene)Ru(Se2C2B10H10) (1), [(p-cymene)RuCl(Se-SeC2B10H11)][(p-cymene)Ru(Se2C2B10H10)] (2), [(p-cymene)Ru-2(Se2C2B10H10)(2)][(p-cymene)Ru(Se2C2B10H9)] (3), and [(p-cymene)Ru(Se2C2B10H9) Ru(Se2C2B10H10)](2) (4). 2 contains a rhombic Ru2Se2 core and can be considered as an adduct of the two 16e half-sandwich monomers (p-cymene)Ru(Se2C2B10H10) (1) and (p-cymene)RuCl(Se-SeC2B10H11). In 3 three o-carborane-1,2-diselenolate ligands bridge the adjacent Ru atoms and one [Se2C2B10H9](3-) unit is in a tridentate binding mode with a Ru-B bond. In 4, two identical dinuclear (p-cymene)Ru-2(Se2C2B10H9)(Se2C2B10H10) subunits connect to each other through two Se atoms of two individual [Se2C2B10H10](2-) ligands and a metal-induced B-H activation occurs as well. However, if the above reaction mixture is exposed to air, the unexpected product [(p-cymene)Ru](2)(Se2C2B9H10)Ru-2(Se2C2B10H10)(3)(mu-O) (5) can be isolated in moderate yield. It contains a novel Ru4Se8O core generated from three [Se2C2B10H10](2-), one nido-[Se2C2B9H10](3-), and one mu-oxo unit. Complexes 2-5 have been characterized by elemental analyses, mass and NMR spectra, and X-ray crystallography.