| 251321-37-6

• CAS: 251321-37-6
• 化学式: C₃₀H₄₅ORu₃
• 分子量: 724.897
• InChiKey: IWZXAJLPLBMDKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 air 作用下， 以 水 为溶剂， 生成 [(η6-C6Me6)2(η6-C6H6)Ru3(μ2-H)3(μ3-O)](1+)
  参考文献：
  名称：

  Supramolecular cluster catalysis: facts and problems

  摘要：

  By checking the chemistry underlying the concept of "supramolecular cluster catalysis" we identified two major errors in our publications related to this topic, which are essentially due to contamination problems. (1) The conversion of the "closed" cluster cation [H3Ru3(C6H6K6Me6)(2)(O)](-) (1) into the "open" cluster cation [H2Ru3(C6H6)(C6Me6)(2)(O)(OH)](-) (2), which we had ascribed to a reaction with water in the presence of ethylbenzene is simply an oxidation reaction which occurs in the presence of air. (2) The higher catalytic activity observed with ethylbenzene. which we had erroneously attributed to the "open" cluster cation [H2Ru3(C6H6)(C6Me6)(2)(O)(OH)](-) (2),was due to the formation of RuO2 (.) nH(2)O, caused by a hydroperoxide contamination present in ethylbenzene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.032
• 作为产物：
  描述：

  [(η6-C6Me6)2(η6-C6H6)Ru3(μ2-H)3(μ3-O)](1+) 、 氢气 以 重水 为溶剂， 生成
  参考文献：
  名称：

  Supramolecular cluster catalysis: facts and problems

  摘要：

  By checking the chemistry underlying the concept of "supramolecular cluster catalysis" we identified two major errors in our publications related to this topic, which are essentially due to contamination problems. (1) The conversion of the "closed" cluster cation [H3Ru3(C6H6K6Me6)(2)(O)](-) (1) into the "open" cluster cation [H2Ru3(C6H6)(C6Me6)(2)(O)(OH)](-) (2), which we had ascribed to a reaction with water in the presence of ethylbenzene is simply an oxidation reaction which occurs in the presence of air. (2) The higher catalytic activity observed with ethylbenzene. which we had erroneously attributed to the "open" cluster cation [H2Ru3(C6H6)(C6Me6)(2)(O)(OH)](-) (2),was due to the formation of RuO2 (.) nH(2)O, caused by a hydroperoxide contamination present in ethylbenzene. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.12.032