acetatobromo(2,2'-dipyridylamine)copper(II) | 189204-38-4

• 英文名称: acetatobromo(2,2'-dipyridylamine)copper(II)
• CAS: 189204-38-4
• 化学式: C₁₂H₁₂BrCuN₃O₂
• 分子量: 373.696
• InChiKey: FLEGTDOPCWOUJC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.02
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  77.94
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  bromocarbonyl(2,2'-dipyridylamine)copper(I) 、 溶剂黄146 在 O₂ 作用下， 以 二氯甲烷 为溶剂， 生成 acetatobromo(2,2'-dipyridylamine)copper(II)
  参考文献：
  名称：

  Ugozzoli, Franco; Lanfredi, Anna Maria Manotti; Marsich, Nazario, Inorganica Chimica Acta, 1997, vol. 256, p. 1 - 8

  摘要：

  DOI：

文献信息

• Copper(II)nitrito complexes with 2,2′-dipyridylamine. Crystal structures of the [(acetato)(2,2′-dipyridylamine)(nitrito-O,O′)copper(II)] and [(2,2′-dipyridylamine) (nitrito-O,O′)(μ-nitrito-O)copper(II)]2·2(acetonitrile)
  作者：Annamaria Camus、Nazario Marsich*、Anna Maria Manotti Lanfredi*、Franco Ugozzoli、Chiara Massera

  DOI：10.1016/s0020-1693(00)00213-9

  日期：2000.11

  Abstract The preparation and characterization of some copper(II)nitrito complexes with 2,2′-dipyridylamine (dipyam) are reported. The X-ray diffraction crystal structures of the [Cu(CH3COO)(dipyam)(ONO-O,O′)] (I) and [Cu(dipyam)(ONO-O,O′)(μ-ONO-O)]2·2CH3CN (II) complexes have been investigated. I consists of two crystallographically independent [Cu(acetato)(dipyam)(ONO)] neutral complexes, self-assembled

  摘要报道了一些2,2'-联吡啶胺（dipyam）的亚硝酸铜（II）配合物的制备和表征。[Cu（CH3COO）（dipyam）（ONO-O，O'）]（I）和[Cu（dipyam）（ONO-O，O'）（μ-ONO-O）的X射线衍射晶体结构研究了] 2·2CH3CN（II）配合物。我由两个晶体学上独立的[Cu（乙酰基）（双嘧啶）（ONO）]中性配合物组成，它们由超分子四聚体单元中的合作NH⋯O和CH⋯O分子间相互作用自组装。每个铜原子均表现出N2O2供体组的四面体形扭曲的方基几何结构，顺式单齿亚硝基和乙酰基的第二个氧原子几乎在轴向位置上弱结合。II是含有顺式-单齿和O-桥接的亚硝基配体的双核亚硝基铜（II）衍生物的罕见实例。每种金属离子都与来自亚硝基桥的基础氧占据中心对称络合物轴向位点的方金字塔形配位发生扭曲。双嘧啶氨基和乙腈分子之间的H键可防止双核配合物的自组装。
• Synthesis and crystal structure of some (2,2′-dipyridylamine)(carboxylato)(phenoxo)copper(II) complexes with rather unusual phenoxo ligands
  作者：Alessandro Facchinetti、Nazario Marsich、Annamaria Camus、Franco Ugozzoli、Chiara Massera、Anna Maria Manotti Lanfredi

  DOI：10.1016/s0020-1693(01)00571-0

  日期：2001.11

  Some ternary Cu(dipyam)(OOCR)(OR) complexes (dipyam = 2,2'-dipyridylamine; RCOO- = acetate, benzoate, cmb (2-chloro-5-methylthio-benzoate), mta (methylthioacetate), min (2-methylthio-nicotinate); OR- = pnp (p-nitrophenolate), dcp (2,6-dichlorophenolate), tcp (2,4,6-trichlorophenolate)) have been synthesized. Their IR spectra are included and the X-ray diffraction structure is given for the crystals of [Cu(dipyam)(OOCCH3)(dcp)] (I), [Cu(dipyam)(mta)(dcp)] (II). [Cu(dipyam)(mtn)(dcp)] (III) and [Cu(dipyam)(cmb)(tcp)] (IV). The copper coordination is square pyramidal in 1, with a rather rare axial position of the phenolate ligand, while in II and III is distorted octahedral with equatorial phenolate and weak apical bonds (II Cl, S; III Cl, O). The copper coordination in IV can be better described as square planar, but with distortion toward a flattened tetrahedral geometry and with a rather long apical Cu-O distance, involving an oxygen of the carboxylate ion. The entrance of the phenolate in an axial or equatorial position is due to the geometry imposed to the complex by the auxiliary ligand. (C) 2001 Elsevier Science B.V. All rights reserved.