Crossed-beam studies of energy and angular distributions of organometallic reactions: decarbonylation of acetaldehyde by iron(I) and chromium(I)
作者:D. M. Sonnenfroh、J. M. Farrar
DOI:10.1021/ja00272a065
日期:1986.6
and dynamics of the reactions of gas-phase transition-metal ions with organic molecules are topics of active research and speculation at present. In the present work, the authors report the first crossed-beam studies of gas-phase transition-metal ion chemistry, demonstrating that product kineticenergy and angular distributions probe the potential energy surface topology of simple carbon-carbon bond