trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NHCH2Ph)] | 606100-18-9

• 英文名称: trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NHCH2Ph)]
• CAS: 606100-18-9
• 化学式: C₂₀H₂₃Cl₂FeNPt
• 分子量: 599.242
• InChiKey: MCMDMECDQBBJLQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NHCH2Ph)] 、 重水 以 氘代氯仿 为溶剂， 生成 trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NDCH2Ph)]
  参考文献：
  名称：

  Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro{(N-ferrocenyl methyl)amine}(η2-ethene)platinum] complexes

  摘要：

  A series of complexes of the type trans-W[PtCl2(eta(2)-ethene)(N-ferrocenyl methyl)amine)] complexes, N-ferrocenylmethylamine = [(eta(5)-C-5-H-5)Fe(eta(5)-C-5-H4CH2NHR], R = (Me, Pr-i, Bu-s, Bu-t, CH2Ph, (p-OCH3)Ph, (o-(OCH3)Ph, (p-CH3)Ph, (o-CH3)Ph, (m-CH3)Ph, (p-Cl)Ph) have been synthesized and characterized on the basis of elemental analysis, IR, H-1 and C-13 NMR spectroscopic methods. The CpCH2NHR (Cp = (eta(5) -C5H5)Fe(eta(5)-C5H4), region of the H-1 NMR spectrum of the complexes has been investigated and shown to contain inequivalent methylene protons, NH-CH and Pt-195 -N-CH coupling take place. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00334-7
• 作为产物：
  描述：

  N-benzyl-N-ferrocenylmethyl amine 、 potassium trichloro(ethylene)platinate(II) 在 丙酮 作用下， 以 水 为溶剂， 生成 trans-[PtCl2(η2-ethene)(η5-C5H5)Fe(η5-C5H4CH2NHCH2Ph)]
  参考文献：
  名称：

  Synthesis, characterization, inequivalency of methylene proton and proton lability in the amino ligand of trans-[dichloro{(N-ferrocenyl methyl)amine}(η2-ethene)platinum] complexes

  摘要：

  A series of complexes of the type trans-W[PtCl2(eta(2)-ethene)(N-ferrocenyl methyl)amine)] complexes, N-ferrocenylmethylamine = [(eta(5)-C-5-H-5)Fe(eta(5)-C-5-H4CH2NHR], R = (Me, Pr-i, Bu-s, Bu-t, CH2Ph, (p-OCH3)Ph, (o-(OCH3)Ph, (p-CH3)Ph, (o-CH3)Ph, (m-CH3)Ph, (p-Cl)Ph) have been synthesized and characterized on the basis of elemental analysis, IR, H-1 and C-13 NMR spectroscopic methods. The CpCH2NHR (Cp = (eta(5) -C5H5)Fe(eta(5)-C5H4), region of the H-1 NMR spectrum of the complexes has been investigated and shown to contain inequivalent methylene protons, NH-CH and Pt-195 -N-CH coupling take place. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00334-7